Chemical Sciences

Biographical Details:

Tia Keyes is associate professor of physical chemistry at the School of Chemical Sciences, where she has been a member of academic staff since 2002. Her research interests lie in the fields of molecular spectroscopy & photophysics and in supramolecular & interfacial chemistry. She is particularly interested in applications of these fields to biological problems, including cell imaging/environmental mapping, cell capture, sensing and membrane mimetics. Tia¿s research team are based between the School of Chemical Sciences and the National Biophotonics and Imaging Platform Ireland (NBIPI) www.nbipireland.ie/ which is housed within The National Centre for Sensor Research www.ncsr.ie Tia is an academic member of The Biomedical Diagnostics Institute (www.bdi.ie) and currently co-node leader (Britain and Ireland) on the Biophotonics4life consortium (http://www.biophotonicsworld.org. Tia is also currently coordinator of the National Biophotonics and Imaging Platform at DCU. Collaborators: Prof. Robert Forster, DCU, Prof. Alan M. Bond, Monash University, Australia, Dr Grace Morgan, UCD, Dr. James Rice, UCD. Dr. Tim McCormack, DKIT, Prof. Tony Wedd, University of Melbourne, Australia, Prof Niamh Moran RCSI, Dr Marc Devocelle, RCSI, Prof L Cronin, Univ Glasgow, UK, Prof. Mario Reuben, Univ. of Karlsruhe, Prof Conor Long, DCU, Prof Barry Lentz, University of North Carolina, Chapel Hill, Prof Emmanuel Iwuoha, Univ. of Western Cape, Prof Vickie McKee, Univ of Loughborough, Prof Jane Nelson.

Research Interests:

Key Current Research Interests ¿ Photochemistry and spectroscopy, in particular, electronic, Raman, and time-resolved spectroscopies applied to the study of Electron and Energy Transfers in supramolecular and heterogeneous nano-scale assemblies. ¿ Supramolecular interfacial chemistry, particularly the development of photoactive arrays which incorporate controlled degrees of inter-component, and interfacial communication for solar energy conversion and nanoelectronic devices. ¿ Luminescent polymers and supermolecules for sensing, electrochromics and ECL. ¿ Nanoscale Interfacial platforms for surface enhanced bio-Raman spectroscopy. ¿ Luminescent probes for heterogeneous microenvironments and biomaterials. Vacancies: Currently there are no research vacancies in our group, however, we are always interested in hearing from high quality graduates or postdocs who may be interested in applying with us for Marie Curie Postdoctoral or Postgraduate funding to join our group.

Selected Peer Reviewed Journals

• Giovanni Valenti1, Emmet J O¿Reilly, Andrea McNally, Tia E. Keyes, Massimo Marcaccio, Francesco Paolucci1, Robert J. Forster,. 2013. Electrochemically Induced Release of a Luminescent Probe from a Rhenium-Containing Metallopolymer. ChemPlusChem, In print
• Ciarán Dolan, Roisin Moriarty, Elena Lestini, Marc Devocelle, Robert J. Forster and Tia E. Keyes*. 2013. Cell Uptake and Cytotoxicity of a Novel Cyclometalated Iridium(III) Complex and its Octaarginine Peptide Conjugate. Journal Of Inorganic Biochemistry, 119,, pp65-74.
• M Ahmed, T Byrne, T.E. Keyes. 2013. The Photocatalytic Inactivation Effect of Ag-TiO2 on beta-amyloid Peptide. Journal Of Photochemistry And Photobiology A-chemistry, In print,
• E. Spain, E.; Brennan, H. McArdle, T.E.; Keyes, R.J. Forster,. 2012. High Sensitivity DNA Detection Based on Regioselectively Decorated Electrocatalytic Nanoparticles,. Analytical Chemistry, In Print,
• A. Devdoss, L Dennany, C Dickenson, T.E. Keyes, R.J. Forster. 2012. Highly Sensitive Detection of NADH Using Electrochemiluminescent Nanocomposites Electrochemistry Communications. Electrochemistry Communications, In Print,
• Aaron Martin , Conor Long,Robert J. Forster, Tia E. Keyes. 2012. Near IR Emitting BODIPY Fluorophores with Mega-Stokes Shifts. Chemical Communications, DOI:10.1039/C2CC31150J,
• Anita Venkatanarayanan, Aaron Martin,Tia E. Keyes, Robert J. Forster. 2012. Electrochemiluminescence properties of a carboxy functionalised BODIPY. Electrochemistry Communications, http://dx.doi.org/10.1016/j.elecom.2012.04.025,
• Colm Mallon, Aurora Walshe, Robert J. Forster, Tia E. Keyes, Robert J. Baker. 2012. The Physical Characterisation and Reactivity of the Uranyl Peroxide [UO2(2-O2)(H2O)2].2H2O: Implications for Storage of Spent Nuclear Fuels,. Inorganic Chemistry, 51,, pp8509-8515.
• Colm T. Mallon, Robert J. Forster, andTia E. Keyes. 2012. Reflectance properties of gold nano-cavity spherical and cuboid molded arrays. Proc. SPIE 8424, 84243F,
• Elaine Spain, Brianna Miner, Tia E. Keyes and Robert J. Forster. 2012. . Chemical Communications, 48,, pp838-.
• Emmet J. O¿Reilly, Tia E. Keyes, Robert J. Forster and Lynn Dennany. 2012. New Insights into Electrochemiluminescent enhancement through electrode surface modification,. The Analyst, In Print,
• Frances Lordan James H. Rice, Bincy Jose, Robert J. Forster, and Tia E. Keyes. 2012. Effect of Cavity Architecture on the Surface-Enhanced Emission from Site-Selective Nanostructured Cavity Arrays. Journal Of Physical Chemistry Part C: Nanomaterials And Interfaces, In Print,
• James J. Walsh, Colm Mallon, Alan M. Bond, Tia E. Keyes and Robert J. Forster,. 2012. Enhanced Photocurrent Production from Thin Films of Ru(II) Metallopolymer/Dawson Polyoxotungstate Adducts Under Visible Irradiation. Chemical Communications, In Print,
• James J. Walsh, Qiang Zeng, Robert J. Forster and Tia E. Keyes,. 2012. Highly Luminescent Ru(II) Metallopolymers: Photonic and Redox Properties in Solution and as Thin Films.. Photochemical And Photobiological Sciences, DOI:10.1039/C2PP25134E.,
• Jamie Walsh, Jie Zhu, Robert J, Forster, Tia E. Keyes. 2012. Self Assembled Composites of Luminescent Ru(II) Metallopolymers and the Dawson polyoxometalate ?-[Mo18O54(SO4)2]4-: Photophysics and Visible Sensitization of Photoelectrochemistry.". Dalton Transactions, DOI:10.1039/C2DT30503H,
• P, N. Martinho, T. Lemma, B. Gildea, G. Picardi, H. Müller-Bunz, R. J. Forster, T. E. Keyes, G. Redmond and G. G. Morgan. 2012. Template Assembly of Spin Crossover 1D Nanowires'. Angewandte Chemie-international Edition In English, In Print,
• P. N. Martinho, B. Gildea, M. M. Harris, T. Lemma, A. D. Naik, H. Muller-Bunz, T. E. Keyes, Y. Garcia and G. G. Morgan. 2012. Cooperative Spin Transition in a Mononuclear Manganese(III) Complex. Angewandte Chemie-international Edition In English, In Print,
• Thibault Tabarin, Aaron Martin, Robert J. Forster, Tia E. Keyes,. 2012. Poly-Ethylene Glycol Induced Super-Diffusivity in Lipid Bilayer Membranes,. Soft Matter, DOI:10.1039/C2SM25742D,
• Ute Neugebauer, Lynda Cosgrave, Yann Pellegrin, Marc Devocelle, Robert J. Forster, and Tia E. Keyes. 2012. Membrane permeable luminescent metal complexes for cellular imaging. Proc. SPIE 8427, 84270C (2012),
• A. Ventekanayran, A. Devdoss, T.E. Keyes, R.J. Forster,. 2011. High Sensitivity Carbon Nanotube Based Electrochemiluminescence Sensor Array,. Biosensors & Bioelectronics, In Print,
• A. Devadoss, C. Dickinson, TE Keyes, RJ Forster. 2011. Electrochemiluminescent Metallopolymer-Nanoparticle Composites: Nanoparticle Size Effects. Analytical Chemistry, 83, 6, pp2383-2387.
• A. Venkatanarayanan B.S. O'Connell, A.Devadoss, T.E.Keyes, R.J.Forster. 2011. Potential modulated electrochemiluminescence of ruthenium containing metallopolymer films. Electrochemistry Communications, 13, 5, pp396-.
• B Jose, C.M. Mallon, R.J. Forster, Tia E Keyes. 2011. Regio-Selective Decoration of Nanocavity Metal Arrays: Contributions From Localized and Delocalized Plasmons to Surface Enhanced Raman Spectroscopy. Physical Chemistry Chemical Physics, 13, , pp14705-.
• B. Jose, C. Mallon, , R.J. Forster, T.E. Keyes,. 2011. Assembly of lipid bilayers at Nanocavity Arrays. Chemical Communications, In Print,
• Brennan Jennifer L.; Keyes Tia E.; Forster Robert J. J.. 2011. Electrochemical properties of ruthenium metallopolymer: Monolayer-protected gold cluster nanocomposites,. Journal Of Electroanalytical Chemistry, 662,, pp30-35.
• CM Mallon, RJ Forster & TE Keyes. 2011. Mechanism and Release Rates of Surface Confined Cyclodextrin Guests. The Analyst, In Print,
• Colm T. Mallon, Robert, J. Forster, Tia E Keyes. 2011. Fabrication of Gold Sphere to Cuboid Nanoarrays using PDMS Templates. Chemical Communications, 47, , pp7605-.
• CW. Blackledge, T. Tabarin, R.J. Forster, T.E. Keyes. 2011. Silica Nanoparticles Containing a Rhodamine dye and Multiple Gold Nanorods,. Journal of Nanoparticle Research,, DOI 10.1007/s11051-011-0429-5.
• E. Spain, R.Kojima, RB Kaner, GG. Wallace, J.O'Grady J K. Lacey, T.Barry, T.E. Keyes, R.J Forster. 2011. High sensitivity DNA detection using gold nanoparticle functionalised polyaniline nanofibres. Biosensors & Bioelectronics, 26, , pp2613-2618.
• Elaine Spain, Tia E. Keyes, Robert J. Forster. 2011. Regio Selective Functionalisation of Gold Nanoparticles with DNA. Chemical Communications, In Print,
• Emmet J. O'Reilly, Lynn Dennany, Darren Griffith, Francois Moser, Tia E. Keyes and Robert J. Forster. 2011. Ground and excited state communication within a ruthenium containing benzimidazole metallopolymer. Physical Chemistry Chemical Physics, 13, , pp7064-7070.
• Frances Lordan, James H. Rice, Bincy Jose, Robert J. Forster, and Tia E. Keyes. 2011. Site selective surface enhanced Raman on nanostructured cavities. Applied Physics Letters, 99, , pp033104-.
• Gennaro Picardi, Tia E. Keyes, Robert J. Forster, Conor Long. 2011. Probing the Metal-to-Ligand Charge Transfer First Excited State in (n6-naphthalene)Cr(CO)3 and (n6-phenanthrene)Cr(CO)3 by Resonance Raman Spectroscopy and Density Functional Theory Calculations. Journal Of Physical Chemistry A, In Print,
• James J. Walsh, De-Liang Long, Leroy Cronin, Alan M. Bond, Robert J. Forster and Tia E. Keyes. 2011. Electronic and Photophysical properties of Adducts of [Ru(bpy)3]2+ and Dawson-type Sulfite Polyoxomolybdates a/ß-[Mo18O54(SO3)2]4-. Dalton Transactions, 40, 9, pp2038-2045.
• Jennifer L. Brennan, Tia E. Keyes, Robert J. Forster. 2011. Electrochemical properties of ruthenium metallopolymer: Monolayer-protected gold cluster nanocomposites. Journal Of Electroanalytical Chemistry, In Print,
• Jie Zhu, Qiang Zeng, Shane O'Carroll, Alan M. Bond, Robert Forster and Tia Keyes. 2011. Photocurrent Generation From Thin Films of Ruthenium Metallopolymer:Polyoxometalate Composites Using Visible Excitation. Electrochemistry Communications, In Print,
• Lynn Dennany, Matthias Gerlach, Shane O¿Carroll, Tia E. Keyes, Robert J. Forster and Paolo Bertoncello. 2011. Electrochemiluminescence (ECL) sensing properties of water soluble core-shell CdSe/ZnS quantum dots/Nafion composite films. Journal Of Materials Chemistry, DOI: 10.1039/C1JM12183A,
• M. Ahmed, T.E. Keyes,T. Byrne, C. W. Blackledgea, J. W. Hamilton. 2011. Adsorption and Photocatalytic Degradation of Human Serum Albumin on TiO2 and Ag-TiO2 Films,. Journal Of Photochemistry And Photobiology A-chemistry, 222, , pp123-131.
• C. Mallon, C de Chaumont, N. Moran, RJ Forster, TE Keyes. 2010. Electrochemical Desorption of Fibrinogen from Gold,. Langmuir, 26, 1, pp293-298.
• C. Mallon, T.E. Keyes, & RJ Forster. 2010. Single Nanocavity Electrodes: Fabrication, Electrochemical and Photonic Properties. Chemical Communications, 46, , pp7109-.
• Claudio Zuliani,Darren Walsh, Tia E. Keyes, and Robert J. Forster. 2010. Formation and Growth of Oxide Layers at Platinum and Gold Nano- and Micro-electrodes. Analytical Chemistry, In Print,
• Colm Mallon, Bincy Jose, Robert J Forster, Tia E Keyes. 2010. Protein Nanopatterning and Release from Gold Nanocavity Arrays. Chemical Communications, 46, , pp106-108.
• Devocelle M, Blackmore L, Cosgrave L, Forster, R., Keyes T. 2010. Novel molecular dyes for the labelling of synthetic peptides Journal of Peptide Science. 16, , pp183-.
• EAnitha Devadoss, Calum Dickinson, Tia E. Keyes and Robert J. Forster. 2010. Electrochemiluminescence and Charge Transport Properties of Metallopolymer-Gold Nanocomposites,. Electrochem. Soc. Trans., In Print,
• EC,Reddy, C Blackledge, N. Moran, T.E. Keyes, R.J. Forster, S. O' Neill. 2010. Whole Platelet Analysis by Raman Spectroscopy. Irish Journal Of Medical Science, 179, , ppS301-.
• Frances Lordan, James H. Rice, Bincy Jose, Robert J. Forster, and Tia E. Keyes. 2010. Surface enhanced resonance Raman and luminescence on plasmon active nanostructured cavities. Applied Physics Letters, 97, , pp153110-.
• Lynda Cosgrave, Marc Devocelle, Robert J Forster, Tia E. Keyes. 2010. Multimodal Cell Imaging by Ruthenium Polypyridyl Labelled Cell Penetrating Peptides. Chemical Communications, 46, Highlights in Chemical Biology Article Free Download www.rsc.org/highlightschembiol, pp103-105.
• Q Qiang, A McNally, C Dickinson, R Marthi, TE Keyes, RJ Forster. 2010. Host-Guest Directed Assembly of Gold Nanoparticle Arrays. Langmuir, 26, 2, pp1325-1333.
• RJ Forster, A. Devadoss, A M.Spehar-Deleze TE Keyes. 2010. Nanoparticle-metallopolymer nanocomposites for high brightness electrochemiluminescence assays LUMINESCENCE. 25, 2, pp207-.
• Spehar-Deleze AM, Pellegrin Y, Forster RJ, Tia E. Keyes. 2010. Energy transfer in electroluminescent films: potential sensors for biomedical applications Luminescence. 25, 2, pp199-.
• Agnieszka Kaminska, Robert J Forster, Tia E Keyes. 2009. The Impact of Adsorption of Bovine Pancreatic Trypsin Inhibitor on CTAB protected Gold-Nanoparticle Arrays: A Raman Spectroscopic Comparison with Solution Denaturation. Journal Of Raman Spectroscopy, 41, , pp130-135.
• Andrea McNally, Robert J. Forster & Tia E Keyes. 2009. Interfacial Supramolecular Cyclodextrin-Fullerene Assemblies: Host Reorientation and Guest Stabilization. Pccp Physical Chemistry Chemical Physics, 11, , pp848-.
• Bincy Jose, Ronald Steffan, Robert J. Forster & Tia E Keyes. 2009. Emission Enhancement within Gold Spherical Nanocavity Arrays. Pccp Physical Chemistry Chemical Physics, 11, 46, pp10923-.
• Expanding the Coordination Cage: A Ruthenium (II)-Polypyridine Complex Exhibiting High Quantum Yields under Ambient Conditions". 2009. M. Ruben, F. Schramm, M. Velemir, H.Fliegl, K. Fink, O. Fuhr, Olaf; W. Klopper, Q. Wim Zhi-Rong; T.E. Keyes, S.Finn. Inorganic Chemistry, 48, , pp5677-.
• Min-Kyu Cho, Kelly Aylward, Markus Raab, Heide Daxecker, Colm T. O¡¦Dushlaine, Denis C. Shields, Marc Devocelle Tia Keyes, Lynda Cosgrave, Sarah O¡¦Neill, Kenneth Hun Mok and Niamh Moran,. 2009. Ligand Switching in Cell-Permeable Peptides: Manipulation of the ¿Ñ integrin signature motif, Elise Bernard, Laavanya Parthasarathi,. ACS Chemical Biology, 6, , pp457-.
• R.J. Forster, A Devadoss, A-M. Spehar-Délèze, D. Tanner, David; P. Bertoncello; R. Marthi, T.E. Keyes. 2009. Enhanced Electrochemiluminescence and Charge Transport Through Films of Metallopolymer-Gold Nanoparticle Composites. Langmuir, 26, , pp2130-.
• Yann Pellegrin, Robert J. Forster, Tia E Keyes. 2009. PH DEPENDENT PHOTOPHYSICS AND ROLE OF MEDIUM ON PHOTOINDUCED ELECTRON TRANSFER BETWEEN RUTHENIUM POLYPYRIDYL COMPLEX AND ANTHRAQUINONE.. Inorganica Chimica Acta, 362, , pp1715-.
• Agnieszka Kaminska, Robert J. Forster & Tia E Keyes. 2008. Chemically Bound Gold Nanoparticle Arrays on Silicon: Assembly, Properties and SERS study of Protein Interactions. Pccp Physical Chemistry Chemical Physics, 10, , pp4172-4180.
• Anna-Maria Spehar-Deleze, Ute Neugebauer, Yann Pellegrin, Tia E. Keyes, Robert J. Forster. 2008. Electrochemiluminescent Metallopolymers: Tuning the Emission Wavelength by Energy Transfer Between Two Bound Centres. Electrochemistry Communications, 10, , pp984-.
• Colm T. Mallon, Andrea McNally, Tia E. Keyes, Robert J. Forster,. 2008. Hg-Pt Tunneling Junctions Incorporating Host-Guest Complexes;. Journal Of The American Chemical Society, 130, , pp10002-10007.
• Gavin Sewell, Robert J. Forster, Tia E. Keyes. 2008. Influence of Steric Confinement Within Zeolite Y on Photoinduced Energy Transfer Between [Ru(bpy)3]2+ and Iron Polypyridyl Complexes. Journal Of Physical Chemistry A, 112, 5, pp880-.
• L. Dennany, T.E. Keyes, R.J. Forster,. 2008. Surface Confinement And Its Effects On The Luminescence Quenching Of A Ruthenium Containing Metallopolymer,. The Analyst, 6, , pp753-759.
• Muath Atmeh, Noel R. Russell, Tia E Keyes. 2008. Intramolecular Photoinduced Electron Transfer in a Ruthenium Polypyridyl Functionalised beta-Cyclodextrin Capped with a Hydroxo Bridged Cu(II) Dimer". Polyhedron, 27, 6, pp1690-1698.
• Q. Zeng, T.E. Keyes, R.J. Forster,. 2008. Three Colour Electrochromic Metallopolymer based on a Ruthenium Phenolate Complex. Electrochemistry Communications, 10, 3, pp466-.
• Qiang Zeng, Tia E Keyes, Robert J.Forster. 2008. Redox Induced Switching Dynamics of a Three Colour Electrochromic Metallopolymer Film. Electrochimica Acta, In Print,
• Robert J Forster and Tia E Keyes. 2008. INTERFACIAL PHOTONIC ARRAYS BASED ON TRANSITION METAL COMPLEXES. Coordination Chemistry Reviews, In Print,
• Robert J. Forster, Anita Venkatanarayanan, Anna-Maria Spehar-Délèze, Lynn Dennany, Yann Pellegrin, Tia E. Keyes,. 2008. Ruthenium Amino-phenanthroline Metallopolymer Films Electropolymerised From an Ionic Liquid: Deposition, Electrochemical and Photonic Properties. Langmuir, 24, 19, pp11233-.
• Yann Pellegrin, Robert J. Forster, Tia E Keyes. 2008. pH Modulated Photo-induced Electron Transfer in a {[Ruthenium-Adamantyl] · [beta-cyclodextrin-MethylViologen]} Inclusion Complex. Inorganica Chimica Acta, 27, 6, pp1690-1698.
• Yann Pellegrin, Ute Neugebauer, Marc Devocelle, Robert J. Forster, William Signac, Niamh Moran, and Tia E. Keyes. 2008. Ruthenium Polypyridyl Peptide Conjugates: Membrane Permeable Probes for Cellular Imaging. Chemical Communications, , pp5307-.
• Colm T. Mallon, Robert J. Forster, Andrea McNally, Elena Campagnoli, Zoe Pikramenou & Tia E. Keyes1*. 2007. Surface Immobilized Pyridine ¿Functionalised gamma-Cyclodextrin: Alkanethiol Co-adsorption Induced Reorientation. Langmuir, 23, , pp6997-.
• E.Sheridan, O. Inya-Agha, T.E. Keyes, R.J. Forster,. 2007. Electrodeposited Nobel Metal SERS: Control of Single Nanoparticle Size and Control of Array Inter-particle Spacing,. Plasmonics in Biology and Medicine IV, Editor(s): Tuan Vo-Dinh, Joseph R. Lakowicz Proceedings of SPIE,,
• Geraldine Walsh, Deirdre Leane, Tia E. Keyes, Niamh Moran, Robert Forster, Dermot Kenny, Sarah O¿Neill.. 2007. RAMAN SPECTROSCOPY REVEALS MODIFICATION OF PLATELET alphaIIbbeta3 BY NITRIC OXIDE. Biochemistry, 46, , pp6429-6436.
• M. Atmeh, R.J. Forster, NR Russell, T.E. Keyes. 2007. The Photophysics of a Luminescent Ruthenium Polypyridyl Complex with Pendant beta-cylodextrin; pH Modulation of Lifetime and Photoinduced Electron Transfer. Journal Of Inclusion Phenomena And Molecular Recognition In Chem, 57, 1-4, pp607-612.
• Obianuju Inya-Agha, Darragh Lucey, Robert J. Forster and Tia E. Keyes,. 2007. Non-Invasive Noble Metal Nanoparticle Arrays For Surface Enhanced Raman Spectroscopy of Proteins, P2007, vol 6450. Plasmonics in Biology and Medicine IV, Editor(s): Tuan Vo-Dinh, Joseph R. Lakowicz Proceedings of SPIE,, , pp6450-.
• P.C. Innis, F. Masdarolomoor, L.A.P. Kane-Maguire, R. J. Forster, Tia E. Keyes, G.G. Wallace,. 2007. Photochemical Properties OF Purified POLY(2-METHOXYANILINE-5-SULFONATE) and the Influence of pH, Oxidation State and Oligmeric impurities,. Journal Of Physical Chemistry B, 111, 44, pp12738-12747.
• Robert J. Forster, Yann Pellegrin, Deirdre Leane, Jennifer Brennan and Tia E. Keyes,. 2007. Effect of Deposition Time on the Orientation of [Ru(bpy)2Qbpy]2+ Adsorbed on Platinum. Journal Of Physical Chemistry, 111, C, pp2063-.
• Robert J. Forster,Yann Pellegrin and Tia E. Keyes. 2007. pH Effects on the Rate of Heterogeneous Electron Transfer across a Fluorine Doped Tin Oxide/Monolayer Interface. Electrochemistry Communications, , pp1899-1906.
• Andrea McNally, Robert J. Forster, Noel R. Russell and Tia E. Keyes. 2006. Fullerene bridged metallocyclodextrin donor¿acceptor complexes: optical spectroscopy and photophysics. Journal Of The Chemical Society-dalton Transactions,
• Deirdre Leane and Tia E. Keyes. 2006. Electronic coupling and photochemical stability of O,N bound mononuclear Ru(II) and Os(II) ¿ Hydroquinone complexes. Inorganica Chimica Acta,
• Dennany L, O'Reilly EJ, Keyes TE , Forster RJ. 2006. Electrochemiluminescent monolayers on metal oxide electrodes: Detection of amino acids. Electrochemistry Communications, 8, 10, pp1588-1594.
• J.L. Brennan, Tia E. Keyes, R. J. Forster. 2006. Photonic and Electrochemical Properties of Adsorbed [Ru(dpp)2(Qbpy)]2+ Luminophores. Langmuir, 22, 25, pp10754-.
• L. Dennany, C. Hogan, T.E. Keyes, R.J. Forster,. 2006. Effect of Surface Immobilization on the Electrochemiluminescence of Ruthenium Containing Metallopolymers;. Analytical Chemistry, 78, 5, pp1412-.
• Nigel Fay, Victoria M. Hultgren, Anthony G. Wedd, Tia E. Keyes, Deirdre Leane, Alan M. Bond,. 2006. Sensitization of Photo-Reduction of the Polyoxometalate Anions [S2M18O62]4- (M = Mo, W) in the Visible Spectral Region by the [Ru(bpy)3]2+ Cation. Journal Of The Chemical Society-dalton Transactions, , pp4218-4227.
• Rodney T. Brown, Nicholas C. Fletcher, Mark Nieuwenhuyzen and Tia E. Keyes, Inorg. Chim. Acta,. 2005. The isolation and secondary functionalisation of the mer- and fac-isomers of tris(5-hydroxymethyl-2,2'-bipyridine) complexes of ruthenium(II). Inorganica Chimica Acta, 358, 4, pp1079-.
• Seery MK, Fay N, McCormac T, Dempsey E, Forster RJ, Keyes TE. 2005. Photophysics of ruthenium polypyridyl complexes formed with lacunary polyoxotungstates with iron addenda. Pccp Physical Chemistry Chemical Physics, 7, 19, pp3462-.
• Tia E. Keyes, Deirdre Leane, Robert J. Forster, Niamh Moran, Dermot Kenny,. 2005. New Insights into the molecular mechanisms of thrombosis from high resolution surface enhanced Raman microscopy. Proceedings of the International Society for Optical Engineering,
• Forster RJ, Mulledy D, Walsh DA, Keyes TE,. 2004. Impact of ion solvation on charge transport through [Os(bpy)(2) (H(2)tzt) Cl](+) in the solid state. Pccp Physical Chemistry Chemical Physics, 13, , pp3551-.
• L. OBrien, M. Duati, S. Rau, A.L. Guckian, T.E. Keyes, N.M. OBoyle, A. Serr, H. Gorls and J.G. Vos,. 2004. Synthesis and Characterization of Ruthenium Complexes Containing a Pendent Catechol Ring. Journal Of The Chemical Society-dalton Transactions, , pp514-.
• Michael K. Seery, Liz Guerin, Robert J. Forster, Etienne Gicquel, Victoria Hultgren, Alan M. Bond, Anthony G. Wedd, Tia E. Keyes. 2004. Photophysics of Ruthenium Poylpyridyl Polyoxotungstate Clusters;. Journal Of Physical Chemistry A, 108, 36, pp7399-.
• R.J. Forster, T.E. Keyes,. 2004. Modulation of Heterogeneous Electron Transfer Dynamics across the Electrode/Monolayer Interfaces,. Journal Of Physical Chemistry B, 108, 8, pp2631-.
• Robert J. Forster, Javed Iqbal, Johan Hjelm and Tia E. Keyes. 2004. Solvent Effects on Charge Transport Through Solid Deposits of [Os(4,4'-Diphenyl-2,2'-dipyridyl)2Cl2]. The Analyst,
• T.E. Keyes, H. Hughes, I. Brady,. 2004. Electronic Coupling in Dinuclear Ru(II). Complexes Across Phenolate Bridges with low lying p* orbitals,. Journal Of The Chemical Society-dalton Transactions, , pp334-.
• TE. Keyes, B. Everard, C. Brady, J.G. Vos. 2004. Novel Luminescent Intervalence Dinuclear Ruthenium Complex: Off-On-Off Redox Fluorescence Switch. Journal Of The Chemical Society-dalton Transactions, , pp2314-.
• T.E. Keyes, E. Gicquel, L. Guerin, V. Hultgren, A. Wedd, A.M. Bond. 2003. Evidence for Unusually Strong Electronic Coupling in Polyoxomolybdate-Ruthenium(II)trisbipyridyl Adducts. Inorganic Chemistry, *,
• D. Fayne, T.E. Keyes, R.J. Forster,. 2002. Redox Switching in Solid Deposits : Triazole Osmium Dimer. Journal Of Electroanalytical Chemistry, 75,, pp538-*.
• G.A. Snook, Y.Cooney, T.E. Keyes, R.J. Forster. 2002. Charge Transport Dynamics and Redox Induced Structural Changes Within Solid Deposits of a Ruthenium Dimer. Langmuir, 18,, pp9874-*.
• T.E. Keyes, D. Leane, R.J. Forster, C.G. Coates, J.J. McGarvey, J.G. Vos,. 2002. Redox and Spectroscopic Orbitals in Ru(II) and Os(II) Phenolate Complexes,. Inorganic Chemistry, 22,, pp5721-*.
• D.A. Walsh, T.E. Keyes, C.F. Hogan, R.J. Forster,. 2001. Protonation Effects on Superexchange Across Gold/Osmium Bis-pipyridyl Tetrazine Chloride Monolayer Interfaces. Journal Of Physical Chemistry B, 105,, pp2792-*.
• N. Van Hoof, T. E. Keyes, A. McNally, N. R. Russell. 2001. Preparation of a Novel Biomimetic b-CD-Dimanganese Complex with Covalently Bound Photosensitizer. Chemical Communications, 13,, pp1156-*.
• R.J. Forster, T.E. Keyes. 2001. Tetrazine bridged osmium dimers: Electrochemical vs photoinduced electron transfer. Journal Of Physical Chemistry B, 105,, pp8829-*.
• R.J. Forster, T.E. Keyes,. 2001. Solid-State Osmium Bis-bipyridyl Triazole Chloride Films : Redox Properties and Electrocrystallization,. Journal Of The Chemical Society-faraday Transactions, 3,, pp1336-*.
• S. Fanni, F. M.Weldon, L. Hammarström, E. Mukhtar, T.E. Keyes, and J. G. Vos,. 2001. Photochemically Induced Isomerisation in Ruthenium Polypyridyl Complexes. European Journal Of Inorganic Chemistry, *,, pp529-*.
• Tia E. Keyes, R.J. Forster, A.M. Bond, W. Miaou,. 2001. Electron Self-Exchange on the Solid State: Co-Crystals of Hydroquinone and Bipyridyl Triazole. Journal Of The American Chemical Society, 123,, pp2877-*.
• A.M. Bond, F. Marken, C.T. Williams, D. Beatty, T.E. Keyes, R.J. Forster, J.G. Vos. 2000. Fast Electron Transfer and Anion Transport Processes in the Oxidation of 'Electrochemically Open' microcrystalline Dinuclear complexes at a solid-electrode-Aqueous Electrolyte Interface. Journal Of Physical Chemistry B, 104,, pp1977-*.
• C. Malins, H.G. Glever, T.E. Keyes, J. G. Vos, W.J. Dressic, B.D. McCraith. 2000. Optical pH Sensor Employing Sol-Gel Immobilised Luminescent Ruthenium (II) Polypyridyl Complexes. Sensors And Actuators B-chemical, 67,, pp89-*.
• Fanni S, Keyes TE, O'Connor CM, Hughes, H., Wang, R.Y., Vos, J.G.,. 2000. Excited State Properties of Ruthenium(II) Polypyridyl Complexes Containing Asymmetric Triazole Ligands,. Coordination Chemistry Reviews, 208,, pp77-*.
• Günther Knör, Markus Leirer, Tia E. Keyes, Johannes G. Vos, Arnd Vogler. 2000. 22. Non-luminescent 1,2-Diiminetricarbonylrhenium(I)chloride Complexes. Synthesis, Electrochemical and Spectroscopic Properties of Re(DIAN)(CO)3Cl with DIAN = p-subtituted Bis(arylimino)acenaphthene,. European Journal Of Inorganic Chemistry, 2,, pp529-*.
• R.J. Forster, P. Loughman, T.E. Keyes,. 2000. Effect of Electrode Density of States on the Heterogeneous Electron Transfer Dynamics of Osmium Monolayers. Journal Of The American Chemical Society, 122,, pp11948-*.
• R.J. Forster, T.E. Keyes, A.M. Bond, J. 2000. Protonation Effects on the Structure and Homogeneous Charge Transport Dynamics of Solid-State Osmium Bis-bipyridyl Tetrazine Chloride Films. Journal Of Physical Chemistry B, 104,, pp6389-*.
• R.J. Forster, T.E. Keyes, M. Farrell, D. O¿Hanlon. 2000. Modulation of Lateral Hydrogen Bonding in 1-Amino-2-Sulphonic-4-Hydroxy-Anthraquinone Monolayers,. Langmuir, 16,, pp9871-*.
• R.J. Forster, T.E. Keyes, M. Majda. 2000. Dynamics of Lateral Electron Transfer Within Osmium Containing Langmuir Monolayers. Journal Of Physical Chemistry B, 104,, pp4425-*.
• A. Lees, B. Evard, T.E. Keyes, J.G. Vos, C.J. Kleverlaan, M. Alebbi, C.A. Bignozzi. 1999. Synthesis, Spectroscopy, and Photochemistry, of Ruthenium Triazole Complexes and their Applications as Dye Molecules in Regenerative Solar Cells. European Journal Of Inorganic Chemistry, 12,, pp2309-*.
• Coates CG, McGarvey JJ, Bell SEJ, Jacquet L, Kelly JM, Keyes T.E. 1999. Transient resonance Raman studies of Ru(II) complexes in DNA and in homogeneous media. 19,, pp237-*.
• Coates CG, McGarvey JJ, Bell SEJ, Jacquet L, Kelly JM, Keyes T.E.,. 1999. Transient resonance Raman studies of Ru(II) complexes in DNA and in homogeneous media,. Laser Chemistry, 19,, pp237-*.
• T.E. Keyes, C.M. O'Connor, U.O'Dwyer, C.G. Coates, P. Callaghan, J.J. McGarvey, J.G. Vos,. 1999. Isotope and Temperature Dependence of Dual Emission in a Mononuclear Ru(II) Polypyridyl Complex. Journal Of Physical Chemistry, 103,, pp8915-*.
• Colin G. Coates, Tia E. Keyes, Helen P. Hughes, Pradeep M. Jayaweera, John J. McGarvey, Johannes G. Vos.,. 1998. Resonance Raman and Spectroelectrochemical Studies of Ruthenium Polypyridyl Complexes Containing a Triazole Bridging Ligand: Investigation of the Location of the Lowest Excited State in Mono- and Di-nuclear Complexes containing Pyrazine Moieties. Journal Of Physical Chemistry, 102,, pp5013-*.
• P.G. Coates, T. E. Keyes, J.J. McGarvey, H.P. Hughes, J. G. Vos, P.M. Jayaweera. 1998. Resonance Raman Studies of Ru(II) Complexes in DNA and Homogeneous Media. Coordination Chemistry Reviews, 171,, pp323-*.
• R.J. Forster , T.E. Keyes. 1998. Redox Properties of Ground and Electronically Excited States of [Ru(bpy)2(Qbpy)]2+ Monolayers. Journal Of Physical Chemistry, 102,, pp10004-*.
• R.J. Forster, T.E. Keyes, J.G. Vos. 1998. Hole Superexchange Across a Triazole Bridged Osmium Monolayer/Electrode Interface. The Analyst, *,, pp1905-*.
• S. Fanni, T.E. Keyes, J.G. Vos, S. Campagna. 1998. Photoinduced Charge Separation Through a Negatively Charged Bridge. Inorganic Chemistry, 22,, pp5932-*.
• T.E. Keyes, R.J. Forster, P.M. Jayaweera, J. G. Vos, J.J. McGarvey. 1998. Modulation of electronic coupling in dioxolene bridged dinuclear complexes. Inorganic Chemistry, 22,, pp5925-*.
• T.E. Keyes,C. O¿Connor, J. G. Vos, , J. Chem. Soc. Chem. Comm. 1998. Evidence for Dual Emission and Energy Transfer in Ru(II) Polypyridyl Complexes Containing Pyrazine Triazole. Chemical Communications, *,, pp889-*.
• Tia E. Keyes, Mark Roantree. 1998. Coursework-Pro: An Attempt at Paperless Coursework. *,, pp2180-*.
• T.E. Keyes, M. Niewenhuisen, J.G. Vos. 1997. A 2:1 Co-Crystal of Hydroquinone and 3,5-Bis(pyridin-2-yl)1,2,4-triazole. Acta Crystallographica Section C, C53,, pp1873-*.
• T.E. Keyes, P.M. Jayaweera, J.J. McGarvey and J.G. Vos. 1997. Optical Transitions of Ru(II) Complexes Bound to Hydroquinone in Different Oxidation States. Journal Of The Chemical Society-dalton Transactions, *,, pp1627-*.
• 7. N.T.H. White, T.M. Feehan, J.R.G. Thorne, T.E. Keyes, P. Heathcote and G.S. Beddard. Primary Charge Separation and Energy Transfer in the Photosystem I Reaction Center of Higher Plants, J. Phys. Chem., 100, 12086 1996. 1996. Primary Charge Separation and Energy Transfer in the Photosystem I Reaction Center of Higher Plants. Journal Of Physical Chemistry, 100,, pp12086-*.
• P.M. Jayaweera, T.E. Keyes, J. McGarvey, A.H.R. Al-Obaidi, S.E.J. Bell and J.G. Vos,. 1996. Resonance Raman Studies of Inter-Valence States in Asymmetric Phenolate-Bound Complexes of Ruthenium. *,, pp786-*.
• S. Serroni, S. Campagna, G. Denti, T.E. Keyes, J.G.Vos. 1996. A Tetranuclear Ruthenium(II) Complex Containing Both Electron-Rich and Electron-Poor Bridging Ligands. Absorption Sectrum, Luminescence, Redox Behaviour and Intercomponent Energy Transfer. Inorganic Chemistry, 35,, pp4513-*.
• T. E.Keyes, J. G. Vos, J.A. Kolnaar, J. Haasnoot, J. Reedijk, R. Hage. 1996. Tuning of the Photostability of Bis(2,2'-Biquinoline)Ruthenium(II) Complexes Containing Pyridyltriazole Ligands by Variation of pH. Inorganica Chimica Acta, 245,, pp237-*.
• T.E. Keyes, F. Weldon, E. Muller, P. Pechy, M. Gratzel and J.G Vos,. 1995. Application of Deuteriation to Determine the Location of the Emitting State in Mixed-ligand Ru(II) Polypyridyl Complexes. Journal Of The Chemical Society-dalton Transactions, *,, pp2705-*.
• B.D. MacCraith, C.M. McDonagh, G. O'Keeffe, E.T. Keyes, J.G. Vos, B. O'Kelly and J.F. McGilp. 1993. ¿Fiber Optic Oxygen Sensor Based on Fluorescence Quenching of Evanescent-wave Excited Ruthenium Complexes in Sol-gel derived porous Coatings.¿. The Analyst, 118,, pp385-*.
• R.Wang, T. E. Keyes, R. Hage, R. H. Schmehl and J. G. Vos. 1993. Electrochemically Induced, Reversible, Proton Transfer involving a Quinone/Hydroquinone Redox Couple. Chemical Communications, 21,, pp1652-*.

Selected Books

• J.G. Vos, R.J. Forster, T.E. Keyes. Interfacial Supramolecular Assemblies : Electrochemical and Photophysical Properties, Wiley, 2003.

Selected Chapters

• Tia E. Keyes, Robert J. Forster and Charles Blackledge. 2010. Time resolved spectroscopy of inorganic complexes . Spectroscopic Properties of Inorganic and Organometallic Compounds; Techniques, Materials and Applications Series: SPR Spectroscopic Properties of Inorganic and Organometallic Compounds (RSC), Vol. 41 , pp211-.
• Robert Forster, Paolo Bertoncello & T.E. Keyes. 2008. Electrochemiluminescence ACS,. Advances in Analytical Chemistry,
• Robert J. Forster, Tia E. Keyes. 2006. Ultramicroelectrodes. Handbook of Electrochemistry, pp155-186.
• Tia E Keyes and Robert J Forster. 2006. Spectroelectrochemistry. Handbook of Electrochemistry, ,, pp591-633.
• Forster, R. J. and Keyes, T. E. 2001. Ion Selective Electrode for Environmental Analysis. . Encyclopedia of Analytical Chemistry

Reviews

• Dr Tia E Keyes. .

• T.E. Keyes, 45. Fluorescent Probes in Nanoporous Media, T.E. Keyes, Invited Seminar, Growing Nanotehcnology in Ireland, UCC, September 5th 2003. , Growing Nanotehcnology in Ireland , 05-SEP-03 - , UCC, Cork
• D. Leane, I. Brady, T.E. Keyes, Optical Properties of Ru and Os complexes of hydroquinone and phenol, a comparative study, EuroConference on Molecular Rods, Wires and Switches, 14-SEP-02 - , San Feliu de Guixols, Spain
• E.Gicquel, T. E. Keyes, N. Brady, July 2002, DNA Photocleavage by Novel Oxodiperoxo Complexes., IUPAC conference on Photochemistry,, 11-JUL-02 - , Budapest, Hungary
• T.E. Keyes, A. McNally, , Re-CD-Mn complexes- bimoimetic photosystem II, IUPAC conference on Photochemistry, ,, 11-JUL-02 - , Budapest, Hungary
• T.E. Keyes, Photophysical and Novel Charge Transfer Properties of Polyoxomolybdate-Ruthenium(II)trisbipyridyl Adducts,, 1st FOCAS conference on optical spectroscopy and photochemistry, 25-JUN-02 - , Dublin
• I. Brady, H. Hughes, T.E. Keyes., Electronic Communication in Pyrazinephenolate bridged Ru(II) Complexes, Royal Society of Chemistry, Dalton Discussions,, 13-JAN-02 - , Kloster Banz, Germany.
• E.Gicquel, T. E. Keyes, Mechanism of DNA Photocleavage by Oxodiperoxo Complexes, Royal Society of Chemistry, Dalton Discussions,, 13-JAN-02 - , Kloster Banz, Germany
• L. Guerin, T.E. Keyes,, Geometric Distortions in Excited States of [Os(LL)3]2+ and {Os(LLL)2]2+ Complexes., Euresco Conference on Chemistry and Physics of Multifunctional Materials, 22-SEP-01 - , Acquafredda di Maratea, Italy
• T.E. Keyes, R.J. Forster, A.M. Bond,, Electrochemistry of Crystalline Organic Assemblies, Electrochem 2000,, 12-SEP-00 - , Dublin
• N.Van Hoof, N.R. Russell, R.J. Forster, T.E. Keyes, A Novel Supramolecular Ru-cyclodextrin Complex, a Possible route to fluorescence quenching based on Molecular Recgonition., Euresco Conference: Supramolecular Chemistry: Reactivity and Catalysis in Supramolecular Systems,, 09-SEP-00 - , Urbino, Italy
• T.E. Keyes, Photoinduced Electron Transfers in Novel Supramolecular Complexes, RSC Symposium on Supramolecular Chemistry,, 24-MAR-00 - , Dublin
• R.J. Forster & T.E. Keyes,, Dynamics of Lateral Electron Transfer within Osmium Containing Langmuir Monolayers., Pittcon 2000, 12-MAR-00 - , *