Registry

Module Specifications

Current Academic Year 2012 - 2013
Please note that this information is subject to change.

Module Title Physical Chemistry Laboratory
Module Code CS253
School School of Chemical Sciences
Online Module Resources

Module Co-ordinatorSemester 1: Pat O'Malley
Semester 2: Pat O'Malley
Autumn: Pat O'Malley
NFQ level 8 Credit Rating 5
Pre-requisite None
Co-requisite None
Compatibles None
Incompatibles None
Description
The purpose of this module is the development of manipulative and observational skills through experimental procedures where the emphasis is mainly on the accurate determination of physical parameters. An appreciation of the limitations of the methods employed will be developed by the continual use of error analysis. An understanding of the fundamental principles in physical chemistry by conducting relevant experiments with an emphasis on reasoning and analysis of results.

Learning Outcomes
1. Perform basic Physical Chemistry laboratory experiments
2. Conduct experiments to develop knowledge of Spectroscopy, Kinetics, Electrochemistry and Thermodynamics
3. Record and analyse experimental data in order to make conclusions. For example considering experimental data obtained, to conclude on a first order reaction or a second order reaction
4. Develop and improve report writing skills by presenting weekly reports based on each experiment conducted



Workload Full-time hours per semester
Type Hours Description
Lab60Plan and Conduct Experiments
Directed learning15Reading and study of textbook/ references
Assignment20Weekly reports
Independent learning time30No Description
Total Workload: 125

All module information is indicative and subject to change. For further information,students are advised to refer to the University's Marks and Standards and Programme Specific Regulations at: http://www.dcu.ie/registry/examinations/index.shtml

Indicative Content and Learning Activities
Experiments in Physical Chemistry to address topics including Spectroscopy, Kinetics, Electrochemistry, Thermodynamics..
Experiments to include1. Measurement of force constants of C-H bonds by infra-red spectroscopy.2.Measurement of the visible absorption spectra of dyes in solution and correlation of their absorption maxima using the 'electron-in-a-box' model.3. Determination of the stability constant of the triiodide ion by determining its complex distribution between carbon tetrachloride and water.4. Determination of a phase diagram for a binary mixture, methanol and carbon tetrachloride.5. Kinetics of the alkaline hydrolysis of ethyl benzoate - determination of the order of reaction and the rate constant.6. Acid-catalysed iodination of acetone - investigation of whether the reaction is general acid or specific acid catalysed.7. Thermodynamics of a chemical reaction from EMF measurements.8. Activity coefficients of electrolyte solutions from EMF measurements on a galvanic cell.9. Kinetics of the oxidation of iodide by persulphate - a second order reaction showing the effect of ionic strength on the rate of reaction.10. Redox potential studies on the iron(II)/iron(III) system.11. Absorption of oxalic acid on charcoal.12. Critical micelle concentration of a colloidal electrolyte..

Assessment Breakdown
Continuous Assessment100% Examination Weight0%
Course Work Breakdown
TypeDescription% of totalAssessment Date
Performance evaluationn/a20%n/a
Practical/skills evaluationn/a30%n/a
Report (s) (written / oral)n/a50%n/a
Reassessment Requirement
Resit arrangements are explained by the following categories;
1 = A resit is available for all components of the module
2 = No resit is available for 100% continuous assessment module
3 = No resit is available for the continuous assessment component
This module is category 2
Indicative Reading List
  • DCU: 0, Essential:The Physical Chemistry DCU Laboratory Manual for 2nd year Applied Chemistry students.Supplementary:Physical Chemistry textbook references included in the Laboratory Manual. The 2nd year Physical Chemistry Lecture course as well as recommended t, DCU,
Other Resources
None
Array
Programme or List of Programmes
ACBSc in Chemical and Pharmaceutical Sc.
Timetable this semester: Timetable for CS253
Date of Last Revision28-MAY-09
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