Registry

Module Specifications

Current Academic Year 2012 - 2013
Please note that this information is subject to change.

Module Title	Interfacial and Supramolecular Chemistry
Module Code	CS404
School	School of Chemical Sciences
Online Module Resources
Module Co-ordinator	Semester 1: Tia Keyes Semester 2: Tia Keyes Autumn: Tia Keyes
NFQ level	8	Credit Rating	5
Pre-requisite	None
Co-requisite	None
Compatibles	None
Incompatibles	None

Description

The concepts of supramolecular chemistry particularly applied to interfacial self assembly are presented. This modules elucidates the formation, analytical characterisation and properties of electroactive and photoactive interfacial supramolecular assemblies built using polymeric and monomeric surface active components. It focusses on key analytical methods used to study interfacial assemblies and examples of their applications.

Learning Outcomes

1. To demonstrate detailed understanding of the common methods used to construct functional coatings at interfaces and to evaluate the analytical methods which will yield information on structure and behaviour or such films
2. Calculate surface coverage
3. Demonstrate an understanding of polymer characteristics and formation of polymer films
4. Evaluate electrochemical and photochemical/photophysical reactions of surface films and calculate driving forces for electron and energy transfer for interfacial films or suprmolecular structures

Workload	Full-time hours per semester
*Type*	*Hours*	*Description*
Lecture	36	No Description
Independent learning time	89	No Description
Total Workload: 125

All module information is indicative and subject to change. For further information,students are advised to refer to the University's Marks and Standards and Programme Specific Regulations at: http://www.dcu.ie/registry/examinations/index.shtml

Indicative Content and Learning Activities

Supramolecular and Interfacial Chemistry.
Supramolecular Assembly, Interfacial Supramolecular Assembly, Top Down Bottom up approaches to Nanotechnology. Surface coverage. Polymer characteristics and formation of polymer films. Self-Assembly, Langmuir Blodgett Methods..

Photo and Electroactive Interfacial Films.
Photochemical and Electrochemical Addressability. Dynamics, mechanisms and energetics of energy, electron and ion transfer within interfacial coatings and supramolecular assemblies, plasmonics..

Analytical Methods Applied to Interfacial Assemblies.
Electrochemical Methods, Spectroscopic Methods; HREELS, RAIRS, Raman spectroscopy. Surface topological/Imaging methods; STM, AFM, SEM and NSOM..

Applications of Interfacial Films.
Surface Wetting, molecular Switching, Catalytic surfaces using nanostructured interfaces, electroanalytical (bio)sensor development, photochemical switching, solar energy conversion, batteries and fuel cells..

Assessment Breakdown
Continuous Assessment	0%	Examination Weight	100%

Course Work Breakdown
Type	Description	% of total	Assessment Date

Reassessment Requirement
Resit arrangements are explained by the following categories; 1 = A resit is available for all components of the module 2 = No resit is available for 100% continuous assessment module 3 = No resit is available for the continuous assessment component
This module is category 1

Indicative Reading List

Keyes, Forster & Vos: 0, Interfacial Supramolecular Assemblies, Robert J. Forster, Tia E. Keyes and Johannes G. VosSupramolecular Chemistry, Steed and AtwoodPrinciples of Physical Chemistry, Kuhn and Forsterling Supramolecular Electrochemistry, A. E. Kaifer and M. GomezKaiferSupr,

Other Resources

None

Array

Programme or List of Programmes

BSc in Chemical and Pharmaceutical Sc.

BSc in Analytical Science

BSSA

Study Abroad (DCU Business School)

BSSAO

Study Abroad (DCU Business School)

BSc in Chemistry with French

BSc in Chemistry with German