Publications

Publications

BOOKS

  1. Vos, J.G.; Forster, R.J.; Keyes, T.E. Interfacial Supramolecular Assemblies: Electrochemical and Photophysical Properties, Wiley, 2003. ISBN: 978-0471490715
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BOOK CHAPTERS

  1. Keyes, T.E.; Forster, R.J.; Blackledge, C.W. Time resolved spectroscopy of inorganic complexes. Spectroscopic Properties of Inorganic and Organometallic Compounds; Techniques, Materials and Applications Series: SPR Spectroscopic Properties of Inorganic and Organometallic Compounds, RSC, 2010; Vol. 41, pp211-261. ISBN: 978-1-84973-085-3  DOI: 10.1039/9781849730853-00211
  2. Forster, R.J.; Bertoncello, P.; Keyes, T.E. Electrochemiluminescence ACS. Advances in Analytical Chemistry, 2008. 
  3. Forster, R.J.; Keyes, T.E. Ultramicroelectrodes. Handbook of Electrochemistry, Elsevier, 2006; pp155-186. ISBN: 978-0444519580
  4. Keyes, T.E.; Forster, R.J. Spectroelectrochemistry. Handbook of Electrochemistry,  Elsevier, 2006; pp591-633. ISBN: 978-0444519580
  5. Forster, R.J. and Keyes, T.E. Ion Selective Electrode for Environmental Analysis. Encyclopedia of Analytical Chemistry, Wiley, 2001. ISBN: 9780470027318  DOI: 10.1002/9780470027318.a0837
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JOURNAL PAPERS

2015

  1. Devid, E.; Martinho, P.; Kamalakar, M.; Šalitroš, I.; Prendergast, U.; Dayen, J.-F.; Meded, V.; Lemma, T.; González-Prieto, R.; Evers, F.; Keyes, T.E.; Ruben, M.; Doudin, B.; van der Molen, S. J. 2015 Spin transition in arrays of gold nanoparticles and spin crossover molecules, ACS Nano, In Print, DOI: 10.1021/acsnano.5b01103
  2. Basit, H., Maher, S., Keyes, T.E. 2015 Aqueous-filled polymer microcavity arrays: versatile & stable lipid bilayer platforms offering high lateral mobility to incorporated membrane proteins, Analyst, 2015, In Print, DOI: 10.1039/C4AN02317J
  3. Spain, E., Keyes, T.E., Forster, R.J. 2015 Gold Nanowires and Nanotubes for High Sensitivity Detection of Pathogen DNA, Sensors & Actuators: B. Chemical, , In Print. DOI: 10.1016/j.snb.2015.03.040
  4. Gaul, V., Lentz, B., Moran, N., Keyes, T.E. 2014 The Lateral Diffusion and Fibrinogen Induced Clustering of Platelet Integrin αIIbβ3 Reconstituted into Physiologically Mimetic GUVs, Integrative Biology, 7, pp. 402 - 411. DOI: 10.1039/C5IB00003C
  5. Stewart, A.J., O'Reilly, E.J., Moriarty, R.D., Bertoncello, P., Keyes, T.E., Forster, R.J., Dennany, L. 2015 A Cholesterol Biosensor Based on the NIR Electrogenerated-Chemiluminescence (ECL) of Water-Soluble CdSeTe/ZnS Quantum Dots, Electrochim Acta, 157 , pp 8 - 14. DOI: 10.1016/j.electacta.2015.01.073

2014

  1. Nwankire, C.E., Venkatanarayanan, A., Glennon, T., Keyes, T.E., Forster, R.J., Ducrée, J. 2014 Label Free Impedance Detection of Cancer Cells from Whole Blood; An Integrated Centrifugal Microfluidic Platform, Biosensors and Bioelectronics, 68, pp. 382-9. DOI: 10.1016/j.bios.2014.12.049
  2. Reddy, M.H., Al-Shammaria, R.M., Al-Attar, N., Lopez, S., Keyes, T.E., Rice, J.H. 2014 Graphene oxide intercalation into self-assembled porphyrin J-aggregates, Materials Res Exp, , 1 pp. 045038. DOI: 10.1088/2053-1591/1/4/045038
  3. Jacobs, J., Byrne, A., Gathergood, N., Keyes, T.E., Heuts, J.P.A., Heise, A. 2014 Facile synthesis of fluorescent latex nanoparticles with selective binding properties using amphiphilic glycosylated polypeptide surfactants, Macromolecules , 47 , pp. 7303 - 7310. DOI: 10.1021/ma5020462
  4. Martin, A., Byrne, A., Burke, C.S., Forster, R.J., Keyes, T.E. 2014 Peptide-Bridged Dinuclear Ru(II) Complex for Mitochondrial Targeted Monitoring of Dynamic Changes to Oxygen Concentration and ROS Generation in Live Mammalian Cells. J.Am Chem Soc. 136, pp. 15300-9. DOI: 10.1021/ja508043q
  5. Reddy, M.H., Al-Shammaria, R.M., Al-Attar, N., Lopez, S., Keyes, T.E., Rice, J.H. 2014 . Optical properties of porphyrin: graphene oxide composites. Proc. SPIE 9172 Nanostructured Thin Films VII, 91720P. DOI: 10.1117/12.2061951
  6. Devid, E.J., Martinho, P.N., Kamalakar, M.V., Prendergast, U., Kübel, C., Lemma, T., Dayen, J. F., Keyes, T.E., Doudin, B., Ruben, M., van der Molen, S.J. 2014 The influence of molecular mobility on the properties of Gold Nanoparticle Organic Ligand Networks, Beilstein Journal of Nanotechnology , 5 , pp. 1664–1674. DOI: 10.3762/bjnano.5.177
  7. Adamson, K., Spain, E., Prendergast, U., Forster, R.J., Moran, N., Keyes, T.E. 2014. Ligand Capture and Activation of Human Blood Platelets at Monolayer Modified Gold Surfaces , Biomater. Sci.,, 2, pp. 1509-1520. DOI: 10.1039/C4BM00241E
  8. Molapo, K., Ventakanaryan, A., Baker, P., Iwoha, E., Keyes, T.E., Forster, R.J. 2014. High Efficiency Electrochemiluminescence from Polyaniline:Ruthenium Metal Complex Films, Electrochem. Comm. , 48, pp. 65. DOI: 10.1016/j.elecom.2014.08.022
  9. Spain, E., McCooey, A., Dolan, C., Bagshaw, H., Leddy, N., Keyes, T.E., Forster, R.J. 2014. Electrodeposited gold–copper core–shell nanowires for high sensitivity DNA detection, Analyst, 139, pp. 5504. DOI: 10.1039/C4AN01222D
  10. Damm, S., Carville, N. C., Manzo, M., Gallo, K., Lopez, S., Keyes, T.E., Forster, R.J., Rodriguez, B.J., Rice, J.H. 2014. Formation of ferroelectrically defined Ag nanoarray patterns, Proc. SPIE 9126, Nanophotonics V, 91260Y DOI: 10.1117/12.2051908
  11. Adamson, K, Devocelle, M., Moran, N., Forster, R.J., Keyes, T.E. 2014. RGD Labeled Ru(II) Polypyridyl Conjugates for Platelet Integrin αIIbβ3 Recognition and as Reporters of Integrin Conformation. Bioconjugate Chemistry, 25, pp.928. DOI: 10.1021/bc5000737
  12. Moriarty, R.D., Martin, A., Adamson, K., O'Reilly, E., Mollard, P., Forster, R.J., Keyes, T.E. 2014. Water Soluble, Mega-Stokes Shifted BODIPY fluorophores as Contrast reagents in Cell and Tissue Imaging.Journal of Microscopy,253, pp. 204 DOI: 10.1111/jmi.12111 Front Cover
  13. Basit, H., Lopez, S.G., Keyes. 2014. Fluorescence Correlation and Lifetime Correlation Spectroscopy Applied to the Study of Supported Lipid Bilayer Models of the Cell Membrane. Methods, 68, pp. 286. DOI: 10.1016/j.ymeth.2014.02.005
  14. Mustansara, Y., Walsh, J.J., Keyes, T.E., Proust, A., Rinfray, C., Izzet, G., McCormac, T., Forster, R.J. 2014. Electron Transfer to Covalently Immobilized Keggin Polyoxotungstates on Gold. Langmuir, 30, pp. 4509. DOI:10.1021/la4048648
  15. Reddy, H.V.,Al-Shammari, R.m., Al-Attar, N., Kennedy, E., Rogers, L., Lopez, S.G., Senge, M.O., Keyes, T.E., Rice, J.H. 2014. Micro or nanorod and nanosphere structures derived from a series of phenyl-porphyrins. Physical Chemistry Chemical Physics, 16, pp. 4386. DOI:10.1039/C3CP54936D
  16. Spain, E., Brennan, E., Keyes, T.E., Forster. R.J. 2014 . Dual function metal nanoparticles: Electrocatalysis and DNA capture. Electrochimica Acta, 128 pp.61. DOI:10.1016/10.1016/j.electacta.2013.10.025
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2013

  1. Spain, E., Keyes, T.E., Forster, R.J. 2013. Vapour phase polymerised polyaniline–gold nanoparticle composites for DNA detection.Journal of Electroanalytical Chemistry,711, pp. 38.DOI:10.1016/j.jelechem.2013.08.023
  2. Reddy, H.V., Al-Shammari, R.M., Al-Attar, N., Rogers, L., Lopez, S., Forster, R.J., Senge, M.O., Keyes, T.E., Rice, J.H. 2013. Fractal structures in n-phenyl-porphyrinJ-aggregate films. Materials Chemistry and Physics, 143, pp.963.DOI:10.1016/j.matchemphys.2013.10.030
  3. Wencel, D.; Dolan, C.; Barczak, M.; Keyes, T.E.; McDonagh, C. 2013. Synthesis, tailoring and characterization of silica nanoparticles containing a highly stable ruthenium complex. Nanotechnology, 24, 36, pp. 365705. DOI:10.1088/0957-4484/24/36/365705
  4. Damm, S.; Carville,C.; Manzo, M.; Gallo, K.; Lopez, S.; Keyes, T.E.; Forster, R.J.; Rodriguez, B.J.; Rice, J.H. 2013. Surface enhanced luminescence and Raman scattering from ferroelectrically defined Ag nanopatterned arrays. Applied Physics Letters, 103 pp. 083105 DOI: 10.1063/1.4818910
  5. Walsh, J.J.; Zhu, J.; Bond, A.M.; Forster, R.J.; Keyes, T.E. 2013 Visible Light Sensitized Photocurrent Generation from Electrostatically Assembled Thin Films of [Ru(bpy)3]2+ and the polyoxometalate [W18O54(SO4)2]4-; Optimizing Performance in a low electrolyte media. Journal of Electroanalytical Chemistry, 706, pp. 93–101. DOI: 10.1016/j.jelechem.2013.07.020
  6. Venkatanarayanan, A.; Martin, A.; Molapo, K.M.; Iwuoha, E. I.; Keyes, T.E.; Forster, R.J. 2013. Tuning the electrochemiluminescence potential from immobilised BODIPY by co-reactant selection. Electrochemistry Communications , 31, pp. 116-119. DOI: 10.1016/j.elecom.2013.03.027
  7. Lordan, F.;Damm, S.; Kennedy, E.; Mallon, C.; Forster, R.J.; Keyes, T.E.; Rice, J.H. 2013. The Effect of Ag Nanoparticles on Surface-Enhanced Luminescence from Au Nanovoid Arrays. Plasmonics. DOI: 10.1007/s11468-013-9573-3
  8. Martin, A.; Moriarty, R.D.; Long, Forster, R.J.; Keyes, T.E. 2013. Naphthyridyl-Substituted 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) Luminophores: Photophysics and Application as Molecular Imaging Probes in Live Cells. Asian Journal of Organic Chemistry, 2,9, pp. 763–778. DOI:10.1002/ajoc.201300137
  9. Spain, E.; Keyes, T.E.; Forster, R.J. 2013. Polypyrrole-Gold Nanoparticle Composites for Highly Sensitive DNA Detection.Electrochimica Acta, 109, pp. 102-109. DOI:10.1016/j.electacta.2013.07.018
  10. Spain, E.; McArdle, H.; Keyes, T.E.; Forster, R.J. 2013. Detection of sub-femtomolar DNA based on double potential electrodeposition of electrocatalytic platinum nanoparticles. Analyst, 138, pp. 4340-4344. DOI:10.1039/C3AN00500C
  11. Ahmed,M.; Keyes, T.E.; Byrne, J, A. 2013. The Photocatalytic Inactivation Effect of Ag-TiO2 on beta-amyloid peptide (1-42). Journal of Photochemistry and Photobiology A, 254, pp 1-11. DOI:10.1016/j.jphotochem.2012.12.019
  12. Venkatanarayanan, A.; Keyes, T.E.; Forster, R.J. 2013. Label Free Impedance Detection of Cancer Cells,  Analytical Chemistry, 85, 4, pp 2216-2222. DOI:10.1021/ac302943q
  13. Lordan, F.; Al-Attar, N.; Mallon, C.; Bras, J.; Collet, G.; Forster,R.J.; Keyes, T.E.; Rice, J.H. 2013. Temperature dependence of a1 and b2 type modes in the surface enhanced Raman from 4-Aminobenzenethiol. Chemical Physics Letters, 556, pp 158–162. DOI:10.1016/j.cplett.2012.11.028
  14. Blackmore, L.; Moriarty, R.; Dolan, C.; Adamson, K.; Forster, R.J.; Devocelle, M.; Keyes, T.E. 2013. Peptide Directed Transmembrane Transport and Nuclear Lo-calization of Ru(II) Polypyridyl Complexes in Mammalian Cells. Chemical Communications, 49, 26, pp. 2658-2660. DOI: 10.1039/C3CC40453F
  15. Spain, E.; Keyes, T.E.; Forster, R.J. 2013. DNA sensor based on vapour polymerised PEDOT films functionalised with gold nanoparticles. Biosensors and Bioelectronics, 41, pp. 65-70. DOI:10.1016/j.bios.2012.06.046
  16. Dolan, C.; Moriarty, R.; Lestini, E.; Devocelle, M.; Forster, R.J.; Keyes, T.E. 2013. Cell uptake and cytotoxicity of a novel cyclometalated iridium(III) complex and its octaarginine peptide conjugate. Journal of Inorganic Biochemistry, 119, pp. 65-74. DOI:10.1016/j.jinorgbio.2012.11.001
  17. Mallon, C. T.; Spain, E.; Keyes, T.; Forster, R.J. 2013. DNA Mediated Immobilisation of Electrocatalytic Platinum Nanoparticles in Gold Nanocavity Arrays. Chemical Communications, 49, pp. 1380-1382. DOI: 10.1039/C2CC37632F
  18. Valenti, G.; McNally, A.; O'Reilly, E. J.; Keyes, T.E.; Forster, R.J.; Paolucci, F. 2013. Electrochemically-induced release of luminescent probe from a rhenium containing metallopolymer. ChemPlusChem, 71, 1, pp. 55-61. DOI: 10.1002/cplu.201200193 
  19. O'Reilly, E. J.; Keyes, T.E.; Forster, R.J.; Dennany, L. 2013. Insights into Electrochemiluminescent enhancement through electrode surface modification. Analyst, 138, 2, pp. 677-682. DOI: 10.1039/C2AN36045D
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2012

  1. Zhu, J.; Walsh, J.J.; Mallon, C. T.; Bond, A.M.; Keyes, T.E.; Forster, R.J. 2012. Ruthenium Metallopolymer: Dawson Polyoxomolybdate α-[Mo18O54(SO4)2]4- Adduct Films : Sensitization for Visible Photoelectrocatalysis. Langmuir, 28, 37, pp. 13536-13541. DOI: 10.1021/la300886s
  2. Spain, E.; Miner B.;  Keyes T.E.; Forster, R.J. 2012. Regio selective functionalisation of gold nanoparticles with DNA. Chemical Communications, 48, 6, pp838-840. DOI: 10.1039/C1CC15115K
  3. Spain, E.; Brennan, E.; McArdle, H.; Keyes, T.E.; Forster, R.J. 2012. High Sensitivity DNA Detection Based on Regioselectively Decorated Electrocatalytic Nanoparticles. Analytical Chemistry, 84, 15, pp6471-6476. DOI: 10.1021/ac300458x
  4. Devdoss, A.; Dennany, L.; Dickenson, C.; Keyes, T.E.; Forster, R.J. 2012. Highly Sensitive Detection of NADH Using Electrochemiluminescent Nanocomposites. Electrochemistry Communications, 19, pp43-45. DOI: 10.1016/j.elecom.2012.03.003
  5. Martin, A.; Long, C.; Forster, R.J.; Keyes, T.E. 2012.  Near IR Emitting BODIPY Fluorophores with Mega-Stokes Shifts. Chemical Communications, 48, 45, pp5617-5619. DOI: 10.1039/C2CC31150J
  6. Venkatanarayanan, A.; Martin, A.; Keyes, T.E.; Forster, R.J. 2012. Electrochemiluminescence properties of a carboxy functionalised BODIPY. Electrochemistry Communications, 21, pp46-49. DOI: 10.1016/j.elecom.2012.04.025
  7. Mallon, C. T.; Walshe, A.; Forster, R.J.; Keyes, T.E.; Baker, R.J. 2012. The Physical Characterisation and Reactivity of the Uranyl Peroxide [UO2(h2-O2)(H2O)2].2H2O: Implications for Storage of Spent Nuclear Fuels. Inorganic Chemistry, 51, 15, pp8509-8515. DOI: 10.1021/ic3010823
  8. Lordan, F.; Rice, J.H.; Jose, B.; Forster, R.J.; Keyes, T.E. 2012. Effect of Cavity Architecture on the Surface-Enhanced Emission from Site-Selective Nanostructured Cavity Arrays. Journal Of Physical Chemistry C, 116, 2, pp1784–1788. DOI: 10.1021/jp210343t
  9. Walsh, J.J.; Mallon, C.T.; Bond, A.M.; Keyes, T.E.; Forster, R.J.; 2012. Enhanced Photocurrent Production from Thin Films of Ru(II) Metallopolymer/Dawson Polyoxotungstate Adducts Under Visible Irradiation. Chemical Communications, 48, 30, pp3593-3595. DOI: 10.1039/C2CC17431F
  10. Walsh, J.J.; Zeng, Q.; Forster, R.J.; Keyes, T.E. 2012. Highly Luminescent Ru(II) Metallopolymers: Photonic and Redox Properties in Solution and as Thin Films. Photochemical And Photobiological Sciences, 11, 10, pp1547-1557. DOI: 10.1039/C2PP25134E
  11. Walsh, J.J.; Zhu, J.; Forster, R.J.; Keyes, T.E. 2012. Self-Assembled Composites of Luminescent Ru(II) Metallopolymers and the Dawson polyoxometalate a-[Mo18O54(SO4)2]4-: Photophysics and Visible Sensitization of Photoelectrochemistry. Dalton Transactions, 41, 33, pp9928-9937. DOI: 10.1039/C2DT30503H
  12. Martinho, P.N.; Lemma, T.; Gildea, B.; Picardi, G.; Müller-Bunz, H.; Forster, R.J.; Keyes, T.E.; Redmond, G.; Morgan, G.G. 2012. Template Assembly of Spin Crossover 1D Nanowires'. Angewandte Chemie-international Edition In English, 51, 48, pp.11995–11999. DOI: 10.1002/anie.201205122
  13. Martinho, P.N.; Gildea, B.; Harris, M.M.; Lemma, T.; Naik, A.D.; Muller-Bunz, H.; Keyes, T.E.; Garcia Y.; Morgan, G.G. 2012. Cooperative Spin Transition in a Mononuclear Manganese(III) Complex. Angewandte Chemie-International Edition In English, 124, 50, pp.12765–12769. DOI: 10.1002/ange.201205573
  14. Tabarin, T.; Martin, A.; Forster, R.J.; Keyes, T.E.; 2012. Poly-Ethylene Glycol Induced Super-Diffusivity in Lipid Bilayer Membranes. Soft Matter, 8, 33, pp8743-8751. DOI: 10.1039/C2SM25742D
  15. Venkatanarayanan, A.; Crowley, K.; Lestini, E.; Keyes, T.E.; Rusling, J.F.;Forster, R.J. 2012. High sensitivity carbon nanotube based electrochemiluminescence sensor array. Biosensors and Bioelectronics, 31, 1, pp233-239. DOI: 10.1016/j.bios.2011.10.022
  16. Neugebauer, U.; Cosgrave, L.; Pellegrin, Y.; Devocelle, M.; forster, R.J.; Keyes, T.E. 2012. Multimodal Multiparameter Cell Imaging using Ruthenium Polypyridyl Peptide conjugates. Proc SPIE 2012, 8427, 84270C.
  17. Mallon, C.T.; Forster, R.J.; Keyes, T.E. 2012. Reflactance properties of gold nano cavity spherical and cuboid moulded arrays. Proc SPIE 2012, 8424, 84243F. 
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2011

  1. Jose, B.; Mallon, C.T.; Forster, R.J.; Blackledge, C.W.; Keyes T.E.  2011. Lipid bilayer assembly at a gold nanocavity array. Chemical Communications, 47, 46, pp12530–12532. DOI: 10.1039/C1CC15709D
  2. Jose, B.; Mallon, C.T.; Forster, R.J.; Keyes T.E. 2011. Regio-selective decoration of nanocavity metal arrays: contributions from localized and delocalized plasmons to surface enhanced Raman spectroscopy.  Physical Chemistry Chemical Physics, 13, 32, pp14705–14714. DOI: 10.1039/C1CP20979E
  3. Blackledge, C.W.; Tabarin, T.; Masson, E.; Forster, R.J.; Keyes, T.E. 2011. Silica nanoparticles containing a rhodamine dye and multiple gold nanorods.  Journal of Nanoparticle Research, 13, 10, pp4659–4672. DOI: 10.1007/s11051-011-0429-5
  4. Brennan, J.L.; Keyes, T.E.; Forster, R.J. 2011. Electrochemical properties of ruthenium metallopolymer: Monolayer-protected gold cluster nanocomposites. Journal of Electroanalytical Chemistry, 662, 1, pp30–35. DOI: 10.1016/j.jelechem.2011.02.024
  5. Dennany, L.; Gerlach, M.; O’Carroll, S.; Keyes, T.E.;  Forster, R.J.; Bertoncello, P. 2011. Electrochemiluminescence  (ECL) sensing properties of water soluble core-shell CdSe/ZnS quantum dots/Nafion composite films.  Journal Materials Chemistry, 21, 36, pp13984-13990. DOI: 10.1039/C1JM12183A
  6. Dennany, L.; Innis, P.C.; McGovern, S.T.; Wallace, G.G.; Forster, R.J. 2011. Electronic interactions within composites of polyanilines formed under acidic and alkaline conditions. Conductivity, ESR, Raman, UV-vis and fluorescence studies.  Physical Chemistry Chemical Physics,13, 8, pp3303–3310. DOI: 10.1039/c0cp00699h
  7. Devadoss, A.; Dickinson, C.; Keyes, T.E.; Forster, R.J. 2011. Electrochemiluminescent Metallopolymer-Nanoparticle Composites: Nanoparticle Size Effects.  Analytical Chemistry, 83, 6, pp2383–2387. DOI: 10.1021/ac102697c
  8. Zhu, J.; Zeng, Q.; O'Carroll, S.; Bond, A.M.; Keyes, T.E.; Forster, R.J. 2011. Photocurrent generation from thin films of ruthenium metallopolymer: polyoxometalate adducts using visible excitation.  Electrochemistry Communications, 13, 9, pp899–902. DOI: 10.1016/j.elecom.2011.02.010
  9. Lordan, F.; Rice, J.H.; Jose, B.; Forster, R.J.; Keyes, T.E. 2011. Site selective surface enhanced Raman on nanostructured cavities.  Applied Physics Letters, 99, pp033104. DOI: 10.1063/1.3615282
  10. Mallon, C.T.; Forster, R.J.; Keyes, T.E. 2011. Mechanism and release rates of surface confined cyclodextrin guests. Analyst, 136, 23, pp5051-5057. DOI: 10.1039/C1AN15650K
  11. Mallon, C.T.; Forster, R.J.; Keyes, T.E. 2011. Fabrication of gold sphere to cuboid nanoarrays using PDMS templates. Chemical Communications,47, 27, pp7605–7607. DOI: 10.1039/C1CC11495F
  12. O’Reilly, E.J.; Dennany, L.; Griffith, D.; Moser, F.;  Keyes, T.E.; Forster, R.J. 2011. Ground and excited state communication within a ruthenium containing benzimidazole metallopolymer. Physical Chemistry Chemical Physics, 2011, 13, 15, pp7095–7101. DOI: 10.1039/C0CP02638G
  13. Picardi, G.; Keyes, T.E.; Forster, R.J.; Long, C. 2011. Probing the Metal-to-Ligand Charge Transfer First Excited State in (η6-Naphthalene)Cr(CO)3 and (η6-Phenanthrene)Cr(CO)3 by Resonance Raman Spectroscopy and Density Functional Theory Calculations. Journal of Physical Chemistry A, 115, 42, pp11641–11651. DOI: 10.1021/jp206466b
  14. Yuk, J.S.; O’Reilly, E.; Forster, R.J.; MacCraith, B.D.; McDonagh, C. 2011. Demonstration of surface plasmon-coupled emission using solid-state electrochemiluminescence. Chemical Physics Letters, 513, 1-3, pp112–117. DOI: 10.1016/j.cplett.2011.07.083
  15. Spain E.; Kojima, R.; Kaner, R.B.; Wallace, G.G.; O’Grady, J.; Lacey, K.; Barry, T.; Keyes, T.E.; Forster, R.J. 2011. High sensitivity DNA detection using gold nanoparticle functionalised polyaniline nanofibres. Biosensors and Bioelectronics, 26, 5, pp2613–2618. DOI: 10.1016/j.bios.2010.11.017
  16. Venkatanarayanan, A.; O'Connell, B.S.; Devadoss, A.; Keyes, T.E.; Forster, R.J. 2011. Potential modulated electrochemiluminescence of ruthenium containing metallopolymer films. Electrochemistry Communications, 13, 5, pp396–398. DOI: 10.1016/j.elecom.2011.01.031
  17. Walsh, J.J.;  Long,D.L.; Cronin, L.; Bond, A.M.; Forster, R.J.; Keyes, T.E. 2011. Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4-Dalton Transactions, 40, 9, pp2038 – 2045. DOI: 10.1039/C0DT01540G
  18. Ahmeda, M.H.; Keyes, T.E.; Byrne, J.A.; Blackledge, C.W.; Hamilton, J.W. 2011. Adsorption and photocatalytic degradation of human serum albumin on TiO2 and Ag–TiO2 films. Journal of Photochemistry and Photobiology A: Chemistry, 222, 1, pp123– 131. DOI: 10.1016/j.jphotochem.2011.05.011
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2010

  1. Kaminska, A.; Forster, R.J.; Keyes,T.E. 2010. The impact of adsorption of bovine pancreatic trypsin inhibitor on CTAB-protected gold nanoparticle arrays: a Raman spectroscopic comparison with solution denaturation. Journal of Raman Spectroscopy, 41, 2, pp130–135. DOI: 10.1002/jrs.2477
  2. Cosgrave, L.; Devocelle, M.; Forster, R.J.; Keyes, T.E. 2010. Multimodal cell imaging by ruthenium polypyridyl labelled cell penetrating peptides. Chemical Communications, 46, 1, pp103–105. DOI: 10.1039/B918611E
  3. Devadoss, A.;  Spehar-Deleze, A.M.; Tanner, D.A.; Bertoncello, P.; Marthi, R.; Keyes, T.E.; Forster, R.J. 2010. Enhanced Electrochemiluminescence and Charge Transport Through Films of Metallopolymer-Gold Nanoparticle Composites. Langmuir, 26, 3, pp2130–2135. DOI: 10.1021/la902676p
  4. Zuliani, C.; Walsh, D.A.; Keyes, T.E.; Forster, R.J. 2010. Formation and Growth of Oxide Layers at Platinum and Gold Nano- and Microelectrodes. Analytical Chemistry, 82, 17, pp7135–7140. DOI: 10.1021/ac101728a 
  5. Lordan, F.; Rice, J.H.; Jose, B.; Forster,R.J.; Keyes, T.E. 2010. Surface enhanced resonance Raman and luminescence on plasmon active nanostructured cavities. Applied Physics Letters, 97, pp153110. DOI: 10.1063/1.3500836 
  6. Mallon, C.T.; Zuliani, C.; Keyes, T.E.; Forster, R.J. 2010. Single nanocavity electrodes: fabrication, electrochemical and photonic properties. Chemical Communications, 46, 38, pp7109–7111. DOI: 10.1039/C0CC00418A 
  7. Mallon, C.T.; Jose, B.; Forster, R.J.; Keyes, T.E. 2010. Protein nanopatterning and release from gold nano-cavity arrays. Chemical Communications, 46, 1, pp106–108. DOI: 10.1039/B919352A
  8. Mallon, C.T.; De Chaumont, C.; Moran, N.; Keyes, T.E.; Forster, R.J. 2010. Electrochemical Desorption of Fibrinogen from Gold.  Langmuir, 26, 1, pp293–298. DOI: 10.1021/la902115e
  9. Zeng Q.; Marthi, R.; McNally, A.; Dickinson, C.; Keyes, T.E.; Forster, R.J. 2010. Host-Guest Directed Assembly of Gold Nanoparticle Arrays. Langmuir, 26, 2, pp1325–1333. DOI: 10.1021/la902258s
  10. Devadoss, A.; Dickinson, C.; Keyes, T.E.; Forster, R.J. 2010. Electrochemiluminescence and Charge Transport Properties of Metallopolymer-Gold Nanocomposites.  The Electrochemical Society Transactions, 25, 24, pp137-152. DOI: 10.1149/1.3316121
  11. Devadoss, A.; Spehar-Délèze, A.M.; Tanner, D.A.; Bertoncello, P.; Marthi, R.; Keyes, T.E.; Forster, R.J. 2010. Enhanced Electrochemiluminescence and Charge Transport Through Films of Metallopolymer-Gold Nanoparticle Composites. Langmuir26, 3, pp2130–2135. DOI: 10.1021/la902676p

2009

  1. McNally, A.; Forster, R.J. ; Keyes, T.E. 2009. Interfacial supramolecular cyclodextrin-fullerene assemblies: host reorientation and guest stabilization.  Physical Chemistry Chemical Physics, 11, 5, pp848–856. DOI: 10.1039/B810772F
  2. Pellegrin, Y.; Forster, R.J. ; Keyes, T.E. 2009. pH Dependent photophysics and role of medium on photoinduced electron transfer between ruthenium polypyridyl complex and anthraquinone. Inorganica Chimica Acta, 362, 6, pp1715–1722. DOI: 10.1016/j.ica.2008.08.008
  3. Dennany, L.; O’Reilly, E.J.; Innis, P.C.; Wallace, G.G.; Forster, R.J. 2009. Solid State Photochemistry of Novel Composites Containing Luminescent Metal Centers and Poly(2-methoxyaniline-5-sulfonic acid). Journal of Physical Chemistry B, 113, 21, pp7443–7448. DOI: 10.1021/jp901808d
  4. Jose, B.; Steffen, R.; Neugebauer, U.; Sheridan, E.; Marthi, E.; Forster, R.J.; Keyes, T.E. 2009.  Emission enhancement within gold spherical nanocavity arrays. Physical Chemistry Chemical Physics, 11, 46, pp10923–10933. DOI: 10.1039/B908385E
  5. Bernard, E.; Parthasarathi, L.; Cho, M.K.; Aylward, K.; Raab, M.; Daxecker, H.; O’Dushlaine, C.T.; Shields, D.C.; Devocelle, M.; Keyes, T.E.; Cosgrave, L.; O’Neill, S.; Mok, K.H.; Moran, N. 2009. Ligand Switching in Cell-Permeable Peptides: Manipulation of the Integrin Signature Motif. ACS Chemical Biology, 4, 6, pp457–471. DOI: 10.1021/cb8002623
  6. Dennany, L.; Wallace, G.G.; Forster, R.J. 2009. Luminescent Metal Complexes within Polyelectrolyte Layers: Tuning Electron and Energy Transfer. Langmuir,25, 24, pp14053–14060. DOI: 10.1021/la901661v
  7. Schramm, F.; Meded, V.; Fliegl, H.; Fink, K.; Fuhr, O.; Qu, Z.; Klopper, K.; Finn, S.; Keyes, T.E.; Ruben, M. 2009. Expanding the Coordination Cage: A Ruthenium(II)−Polypyridine Complex Exhibiting High Quantum Yields under Ambient Conditions. Inorganic Chemistry48,  13, pp5677–5684. DOI: 10.1021/ic802040v
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2008

  1. Kaminska, A.; Forster, R.J.; Keyes, T.E. 2008. Chemically Bound Gold Nanoparticle Arrays on Silicon: Assembly, Properties and SERS study of Protein Interactions. Physical Chemistry Chemical Physics, 10, 28, pp4172-4180. DOI: 10.1039/b803007c
  2. Spehar-Deleze, A.M.; Neugebauer, U.; Pellegrin, Y.; Keyes, T.E.; Forster, R.J. 2008. Electrochemiluminescent Metallopolymers: Tuning the Emission Wavelength by Energy Transfer Between Two Bound Centres.  Electrochemistry Communications, 10, 7, pp984-986. DOI: 10.1016/j.elecom.2008.03.001
  3. Mallon, C.T.; McNally, A.; Keyes, T.E.; Forster, R.J. 2008. Hg-Pt Tunnelling Junctions Incorporating Host-Guest Complexes. Journal Of The American Chemical Society, 130, 30, pp10002-10007. DOI: 10.1021/ja8011319
  4. Sewell, G.; Forster, R.J.; Keyes.T.E. 2008. Influence of Steric Confinement Within Zeolite Y on Photoinduced Energy Transfer Between [Ru(bpy)3]2+ and Iron Polypyridyl Complexes. Journal Of Physical Chemistry A, 112, 5, pp880-888. DOI: 10.1021/jp077542o
  5. Dennany, L.; Keyes, T.E.; Forster.R.J.2008. Surface Confinement And Its Effects On The Luminescence Quenching Of A Ruthenium Containing Metallopolymer. Analyst, 133, 6, pp753-759. DOI: 10.1039/B718505G
  6. Atmeh, M.; Russell, N.R.; Keyes, T.E. 2008. Intramolecular Photoinduced Electron Transfer in a Ruthenium Polypyridyl Functionalised beta-Cyclodextrin Capped with a Hydroxo Bridged Cu(II) Dimer. Polyhedron, 27, 6, pp1690-1698. DOI: 10.1016/j.poly.2008.02.002
  7. Zeng, Q.; Keyes, T.E.; Forster, R.J. 2008. Three Colour Electrochromic Metallopolymer based on a Ruthenium Phenolate Complex. Electrochemistry Communications, 10, 3, pp466–470. DOI: 10.1016/j.elecom.2008.01.009
  8. Zeng, Q.; Keyes, T.E.; Forster, R.J. 2008. Redox Induced Switching Dynamics of a Three Colour Electrochromic Metallopolymer Film. Electrochemical Acta, 53, 24, pp7033–7038. DOI: 10.1016/j.electacta.2008.05.027
  9. Venkatanarayanan, A.; Spehar-Délèze, A.M.; Dennany, L.; Pellegrin, Y.; Keyes, T.E.; Forster, R.J. 2008. Ruthenium Amino-phenanthroline Metallopolymer Films Electropolymerised From an Ionic Liquid: Deposition, Electrochemical and Photonic Properties.  Langmuir, 24, 19, pp11233–11238. DOI: 10.1021/la8011316
  10. Pellegrin, Y.; Forster, R.J.; Keyes, T.E. 2008. pH Modulated Photo-induced Electron Transfer in a {[Ruthenium-Adamantyl] · [beta-cyclodextrin-MethylViologen]} Inclusion Complex. Inorganica Chimica Acta,361, 9-10, pp1690-1698. DOI: 10.1016/j.ica.2007.12.021
  11. Pellegrin, Y.; Neugebauer, U.; Devocelle, M.; Forster, R.J.; Signac, W.; Moran, N.; Keyes, T.E. 2008. Ruthenium Polypyridyl Peptide Conjugates: Membrane Permeable Probes for Cellular Imaging. Chemical Communications, 42, pp5307–5309. DOI: 10.1039/B810403D
  12. Dennany, L.; O’Reilly, E.J.; Innis, P.C.; Wallace, G.G.; Forster, R.J. 2008. The influence of poly(2-methoxyaniline-5-sulfonic acid) on the electrochemical and photochemical properties of a highly luminescent ruthenium complex. Electrochimica Acta, 53, 13, pp4599–4605. DOI: 10.1016/j.electacta.2007.11.025
  13. Dennany, L.; Innis, P.C.; Wallace, G.G.; Forster, R.J. 2008. Reversible Photoinduced Electron Transfer in a Ruthenium Poly(2-methoxyaniline-5-sulfonic acid) Composite Film. Journal of Physical Chemistry B, 112, 41, pp12907–12912. DOI: 10.1021/jp804213r
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2007

  1. Mallon, C.T.; Forster, R.J.; McNally, A.; Campagnoli, E.; Pikramenou, Z; Keyes, T.E. 2007. Surface Immobilized Pyridine - Functionalised gamma-Cyclodextrin: Alkanethiol Co-adsorption Induced Reorientation. Langmuir, 23, 13, pp6997-7002. DOI: 10.1021/la070212a
  2. Walsh, G.; Leane, D.; Keyes, T.E.; Moran, N.; Forster, R.; Kenny, D.; O’Neill, S. 2007. S-Nitrosylation of Platelet αIIbβ3 As Revealed by Raman Spectroscopy. Biochemistry, 46, 21, pp6429-6436. DOI: 10.1021/bi0620712
  3. Atmeh, M.; Russell, N.R.; Forster, R.J.; Keyes, T.E. 2007. The Photophysics of a Luminescent Ruthenium Polypyridyl Complex with Pendant beta-cylodextrin; pH Modulation of Lifetime and Photoinduced Electron Transfer. Journal Of Inclusion Phenomena and Macrocyclic Chemistry, 2007, 57, 1-4, pp607-612. DOI: 10.1007/s10847-006-9277-9
  4. Innis, P. C.; Masdarolomoor, F.; Kane-Maguire, L. A. P. ; Forster, R. J. ; Keyes, T. E.; Wallace, G.G. 2007. Chemical and Photoluminescence Properties of Purified Poly(2-methoxyaniline-5-sulfonic acid) and Oligomer. Journal Of Physical Chemistry B, 111, 44, pp12738-12747. DOI: 10.1021/jp075395o
  5. Forster, R.J.; Pellegrin, Y.; Leane, D.; Brennan, J.L.; Keyes, T.E. 2007. Effect of Deposition Time on the Orientation of [Ru(bpy)2Qbpy]2+ Adsorbed on Platinum. Journal Of Physical Chemistry, 111, 5, pp2063–2068. DOI: 10.1021/jp064932m
  6. Forster, R.J.; Pellegrin, Y.; Keyes, T.E. 2007. pH Effects on the Rate of Heterogeneous Electron Transfer across a Fluorine Doped Tin Oxide/Monolayer Interface. Electrochemistry Communications, 9, 8, pp1899-1906. DOI: 10.1016/j.elecom.2007.04.022
  7. Bertoncello, P.; Dennany, L.; Forster, R.J.; Unwin, P.R. 2007. Nafion - Tris(2-2'-bipyridyl)ruthenium(II) ultrathin Langmuir - Schaefer films: Redox catalysis and electrochemiluminescent properties. Analytical Chemistry79, 19, pp7549–7553. DOI: 10.1021/ac070811m
  8. Campagnoli, E.; Hjelm, J.; Milios, C.J.; Sjodin, M.; Pikramenou, Z.; Forster, R.J. 2007. Adsorption dynamics and interfacial properties of thiol-based cobalt terpyridine monolayers. Electrochimica Acta, 52, 24, pp6692–6699. DOI: 10.1016/j.electacta.2007.04.096
  9. Carolan, N.; Forster, R.J.; Ó'Fágáin, C. 2007. Covalent attachment of ferrocene to soybean peroxidase glycans: Electron transfer mediation to redox enzymes. Bioconjugate Chemistry, 18, 2, pp524-529. DOI: 10.1021/bc060206a
  10. Sheridan, E.; Hjelm, J.; Forster, R.J. 2007. Electrodeposition of gold nanoparticles on fluorine-doped tin oxide: Control of particle density and size distribution. Journal of Electroanalytical Chemistry, 608, 1, pp1–7. DOI: 10.1016/j.jelechem.2006.11.015
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2006

  1. McNally, A.; Forster, R.J.; Russell, N.R.; Keyes, T.E. 2006. Fullerene bridged metallocyclodextrin donor-acceptor complexes: optical spectroscopy and photophysics. Dalton Transactions, 14, pp1729-1737. DOI: 10.1039/B512830G
  2. Leane, D.; Keyes, T.E. 2006. Electronic coupling and photochemical stability of O,N bound mononuclear Ru(II) and Os(II) - Hydroquinone complexes Inorganica Chimica Acta, 359, 5, pp1627-1636. DOI: 10.1016/j.ica.2005.11.016
  3. Dennany, L.; O'Reilly, E.J.; Keyes, T.E.; Forster, R.J. 2006. Electrochemiluminescent monolayers on metal oxide electrodes: Detection of amino acids.  Electrochemistry Communications, 8, 10, pp1588-1594. DOI: 10.1016/j.elecom.2006.07.022
  4. Brennan, J.L.; Keyes, T.E.; Forster, R.J. 2006. Photonic and Electrochemical Properties of Adsorbed [Ru(dpp)2(Qbpy)]2+ Luminophores. Langmuir, 22, 25, pp10754-10761. DOI: 10.1021/la0611918
  5. Dennany, L.; Hogan, C.; Keyes, T.E.; Forster, R.J. 2006. Effect of Surface Immobilization on the Electrochemiluminescence of Ruthenium Containing Metallopolymers. Analytical Chemistry, 78, 5, pp1412-1417. DOI: 10.1021/ac0513919
  6. Fay, N.; Hultgren, V.M.; Wedd, A.G.; Keyes, T.E.; Leane, D.; Bond, A.M. 2006. Sensitization of Photo-Reduction of the Polyoxometalate Anions [S2M18O62]4- (M = Mo, W) in the Visible Spectral Region by the [Ru(bpy)3]2+ Cation.  Dalton Transactions, 35, pp4218-4227. DOI: 10.1039/B605663F
  7. Bertoncello, P.; Pikramenou, Z.; Unwin P. R.; Forster, R. J. 2006. Adsorption Dynamics, Electrochemical and Electrochemiluminescence Properties of Thiolated Ruthenium 2,2´-Bipyridine Monolayers.  Journal Of Physical Chemistry, 110, 20, pp10063-10069. DOI: 10.1021/jp057276j
  8. O’Connor, M.B.; Killard, A. J.; O’Kennedy, R.; Forster, R. J.; Smyth M. R. 2006. Production and characterization of a polyclonal antibody for Os(II) and Ru(II) polypyridyl complexes. Journal Of Inorganic Biochemistry, 100, 7, pp1252-1259. DOI: 10.1016/j.jinorgbio.2006.02.002
  9. Brennan, J. L.; Keyes, T. E.; Forster, R.J. 2006. Photonic and Electrochemical Properties of Absorbed [Ru(dpp)2(Qbpy)]2+ Luminophores. Langmuir, 22, 25, pp10754-10761. DOI: 10.1021/la0611918
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2005

  1. Hjelm, J.; Handel, R.W.; Hagfeldt, A.; Constable, E.C.; Housecroft, C.E.; Forster, R.J. 2005. Conducting Polymers Containing In-Chain Metal Centers: Electropolymerisation of Oligothienyl-substituted {M(tpy)2} Complexes and In-situ Conductivity Studies, M = Os(II), Ru(II). Inorganic Chemistry, 44, 4, pp1073-1081. DOI: 10.1021/ic049221m
  2. Seery, M.K.; Fay, N.; McCormac, T.; Dempsey, E.; Forster, R.J.; Keyes, T.E. 2005. Photophysics of ruthenium polypyridyl complexes formed with lacunary polyoxotungstates with iron addenda. Physical Chemistry Chemical Physics, 7, 19, pp3426-3433. DOI: 10.1039/B507154B
  3. Brown, R.T.; Fletcher, N.C.; Nieuwenhuyzen, M.; Keyes, T.E. 2005. The isolation and secondary functionalisation of the mer- and fac-isomers of tris(5-hydroxymethyl-2,2'-bipyridine) complexes of ruthenium(II).  Inorganica Chimica Acta, 358, 4, pp1079-1088. DOI: 10.1016/j.ica.2004.10.010
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2004

  1.  Forster, R.J.; Mulledy D.; Walsh D.A.; Keyes T.E. 2004. Impact of ion solvation on charge transport through [Os(bpy)(2) (H(2)tzt) Cl](+) in the solid state.  Physical Chemistry Chemical Physics, 006, 013, pp3551-3556. DOI: 10.1039/B402769H
  2. OBrien, L.; Duati, M.; Rau, S.; Guckian, A.L.; Keyes, T.E.; OBoyle, N.M.; Serr, A.; Gorls, H.; Vos, J.G. 2004. Synthesis and Characterization of Ruthenium Complexes Containing a Pendent Catechol Ring. Dalton Transactions, 4, pp514-522. DOI: 10.1039/B311989K 
  3. Walsh, D.A.; Keyes, T.E.; Forster, R.J. 2004. Modulation of Heterogeneous Electron-Transfer Dynamics across the Electrode/Monolayer Interface.  Journal of Physical Chemistry B, 108, 8, pp2631-2636. DOI: 10.1021/jp036577v
  4. Forster, R.J.; Iqbal, J.; Hjelm, J.; Keyes, T.E. 2004. Solvent Effects on Charge Transport Through Solid Deposits of [Os(4,4'-Diphenyl-2,2'-dipyridyl)2Cl2]. Analyst, 129, 12, pp1186-92. DOI: 10.1039/B414814B
  5. Brady, I.; Leane, D.; Hughes, H.P.; Forster, R.J.; Keyes, T.E. 2004. Electronic properties of Ru(II) complexes bound to a bisphenolate bridge with low lying π* orbitals Dalton Transactions, 2, pp334-341. DOI: 10.1039/B312641B
  6. Keyes, T.E.; Everard, B.; Brady, C.; Vos, J.G.; Brady, C.; McGarvey, JJ.; Jayaweera, P. 2004.  Electronic and photophysical properties of a novel phenol bound dinuclear ruthenium complex: evidence for a luminescent mixed valence state. Dalton Transactions, 15, pp2314-2346. DOI: 10.1039/B405114A
  7. Dennany, L.; Forster, R.J.; White, B.; Smyth, M.; Rusling, J.F. 2004. Direct Electrochemiluminescence Detection of Oxidized DNA in Ultrathin Films containing [Os(bpy)2(PVP)10]2+. Journal Of The American Chemical Society, 126, 28, pp8835-8841. DOI: 10.1021/ja048615+
  8. Forster, R. J.; Walsh, D.; Mano, N.; Mao, F. and Heller, A. J. 2004. Modulating the Redox Properties of an Osmium-Containing Metallopolymer Through the Supporting Electrolyte and Crosslinking. Langmuir, 20, 3, pp862-868. DOI: 10.1021/la035229h
  9. Hjelm, J.; Handel, R.W.; Hagfeldt, A.; Constable, E.C.; Housecroft, C.E.; Forster, R.J. 2004. Electropolymerisation dynamics of a highly conducting metallopolymer: poly-[Os(4 '-(5-(2,2 '-bithienyl))-2,2':6',2''-terpyridine)2]2+. Electrochemistry Communications, 6, 2, pp193-200.  DOI: 10.1016/j.elecom.2003.11.011
  10. O'Connor, M.; Kim, S.N.; Killard, A.J.; Forster, R.J.; Smyth, M.R.; Papadimitrakopoulos F.; Rusling, J. F. 2004. Mediated Amperometric Immunosensing Using Single Walled Carbon Nanotube Forests. Analyst, 129, 12, pp1176-1180. DOI: 10.1039/B412805B
  11. Ramírez-García, S.; Alegret, S.; Céspedes, F.; Forster, R.J. 2004. Carbon Composite Microelectrodes: Charge Percolation and Electroanalytical Performance. Analytical Chemistry, 76, 3, pp503-512. DOI: 10.1021/ac034536p
  12. Seery, M.K.; Guerin, L.; Forster, R.J.; Gicquel, E.; Hultgren, V.; Bond,A.M.; Wedd, A.J; Keyes, T.E. 2004. Photophysics of Ion Clusters Formed between [Ru(bpy)3]2+ and the Polyoxotungstate Anion [S2W18O62]4-. Journal Of Physical Chemistry, 108, 36, pp7399-7405. DOI: 10.1021/jp0482464
  13. Walsh, D.A.; Keyes, T.E.; Forster, R.J. 2004. Modulation of Heterogeneous Electron Transfer Dynamics across the Electrode/Monolayer Interface. Journal Of Physical Chemistry B, 108, 8, pp2631-2631. DOI: 10.1021/jp036577v
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2003

  1. Brennan, J. L.; Forster, R. J. 2003. Laser Light and Electrodes: Interaction Mechanisms and Electroanalytical Applications. Journal Of Physical Chemistry B, 107, 35, pp9344-9350. DOI: 10.1021/jp027189g
  2. Forster, R.J.; Keane, L. 2003. Nanoparticle-metallopolymer Assemblies : Charge Percolation and Redox Properties. Journal Of Electroanalytical Chemistry, 554-555,, pp345-355.  DOI: 10.1016/S0022-0728(03)00258-4
  3. Hjelm, J.; Handel, R.W.; Hagfeldt, A.; Constable, E.C.; Housecroft, C.E.; Forster, R.J. 2003. Conducting Polymers Containing In-Chain Metal Centers : Homogeneous Charge Transport Through A Tetrathienyl-Bridged Os Bis Terpyridine Polymer. Journal Of Physical Chemistry B, 107, 38,  pp10431-10439. DOI: 10.1021/jp035139l
  4. Keyes, T.E.; Gicquel, E.; Guerin, L.; Hultgren, V.; Bond, A.M.; Wedd, A.G.; Forster, R.J. 2003. Photophysical and Novel Charge Transfer Properties of Adducts between [RuII(bpy)3]2+ and [S2Mo18O62]4-. Inorganic Chemistry, 42, 24, pp7897-7905. DOI: 10.1021/ic0206802
  5. Dennany, L.; Forster, R.J.; Rusling, J.F. 2003. Simultaneous Direct Electrochemiluminescence and Catalytic Voltammetry Detection of DNA in Ultrathin Films. Journal Of The American Chemical Society, 125, 17, pp5213-5218. DOI: 10.1021/ja0296529
  6. Williams, E.; Pividori, M.I.; Merkoc, A.; Forster, R.J.; Alegret, S. 2003. Rapid Electrochemical Genosensor Assay Using a Streptavidin Carbon-Polymer Biocomposite Electrode. Biosensors & Bioelectronics, 19, 3, pp165-175. DOI: 10.1016/S0956-5663(03)00171-4
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2002

  1. Walsh, D.A.; Keyes, T.E.; Forster, R.J. 2002. Redox Switching in Solid Deposits: Triazole Osmium Dimer. Journal Of Electroanalytical Chemistry, 538-539,, pp75-85. DOI: 10.1016/S0022-0728(02)01060-4
  2. Brennan J.L.; Howlett, M.; Forster, R.J. 2002. Ground vs. Excited State Electron Transfer: From Adsorbed Monolayers to Trimers in Solution. Faraday Discussions, 121, 391-403, pp441-462. DOI: 10.1039/b110952a
  3. Keyes, T.E.; Leane, D.; Forster, R.J.; Coates, C.G.; McGarvey, J.J.; Nieuwenhuyzen, M.N; Figgemeir, E.; Vos, J.G. 2002. Redox and Spectroscopic Orbitals in Ru(II) and Os(II) Phenolate Complexes. Inorganic Chemistry, 41, 22, pp5721-5732. DOI: 10.1021/ic0202561
  4. Ramirez-Garcia, S.; Alegret, S.; Forster, R.J. 2002. Carbon Composite Electrodes : Surface and Electrochemical Properties.  Analyst, 127, 11, pp1512-1519. DOI: 10.1039/B206201A
  5. Snook, G. A.; Cooney, Y.; Keyes, T. E.; Forster, R. J. 2002. Charge Transport Dynamics and Redox Induced Structural Changes Within Solid Deposits of a Ruthenium Dimer. Langmuir, 18, 25, pp9874-9881. DOI: 10.1021/la025928e
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2001

  1. Walsh, D.A.; Keyes, T.E.; Hogan, C.F.; Forster, R.J. 2001. Protonation Effects on Superexchange Across Gold/Osmium Bis-pipyridyl Tetrazine Chloride Monolayer Interfaces. Journal Of Physical Chemistry B, 105, 14, pp2792-2799. DOI: 10.1021/jp003984n
  2. Van Hoof, N.; Keyes, T.E.; McNally, A.; Russell, N.R. 2001. Preparation of a Novel Biomimetic b-CD-Dimanganese Complex with Covalently Bound Photosensitizer. Chemical Communications, 13, pp1156-1157. DOI: 10.1039/B103363H
  3. Forster, R.J.; Keyes, T.E. 2001. Tetrazine bridged osmium dimers: Electrochemical vs photoinduced electron transfer. Journal Of Physical Chemistry B, 105, 37, pp8829-8837. DOI: 10.1021/jp010948v
  4. Forster, R.J.; Keyes, T.E. 2001. Solid Deposits of Osmium Bis-bipyridyl Triazole Chloride: Redox Properties and Electrocrystallization. Physical Chemistry Chemical Physics, 3,, pp1336-1344. DOI: 10.1039/B008027F
  5. Fanni, S.; Weldon, F.M.; Hammarström, L.; Mukhtar, E.; Keyes, T.E.; Vos, J.G. 2001. Photochemically Induced Isomerisation in Ruthenium Polypyridyl Complexes. European Journal Of Inorganic Chemistry, 2001, 2, pp529-534. DOI: 10.1002/1099-0682(200102)2001:2<529::AID-EJIC529>3.0.CO;2-V
  6. Keyes, T.E.; Forster, R.J.; Bond, A.M.; Miaou, W. 2001. Electron Self-Exchange on the Solid State: Co-Crystals of Hydroquinone and Bipyridyl Triazole. Journal Of The American Chemical Society, 123, 12, pp2877-2884. DOI: 10.1021/ja003966j
  7. Forster, R. J., O'Kelly, J. P. 2001. Dynamics of [Os(bpy)2 (p3p)2]2+ Adsorption and Desorption on Platinum and Gold Microelectrodes. Journal Of The Electrochemical Society, 148, 1, ppE31-E37. DOI: 10.1149/1.1344548
  8. Forster, R.J.; O'Kelly, J.P. 2001. Protonation reactions of anthraquinone-2,7-disulphonic acid in solution and within monolayers. Journal Of Electroanalytical Chemistry, 498, 1-2, pp127-135. DOI: 10.1016/S0022-0728(00)00331-4
  9. Keane, L.; Hogan, C.; Forster, R.J. 2001. Dynamics of charge transport through osmium tris dimethoxy bipyridyl solid deposits. Langmuir, 18, 12, pp4826-4833. DOI: 10.1021/la010927s
  10. Keyes; T. E., Forster, R. J., Bond; A. M. 2001. Electron Self-Exchange in the Solid-State: Cocrystals of Hydroquinone and Bipyridyl Triazole. Journal Of The American Chemical Society, 123, 12, pp2877-2884. DOI: 10.1021/ja003966j
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2000

  1. Bond, A.M.; Marken, F.; Williams, C.T.; Beattie, D. A.; Keyes, T.E.; Forster, R.J.; Vos, J. G. 2000. Unusually Fast Electron and Anion Transport Processes Observed in the Oxidation of Electrochemically Open Microcrystalline [{M(bpy)2}{M'(bpy)2}(m-L)](PF6)2 Complexes (M, M' = Ru, Os; bpy = 2,2'-bipyridyl; L = 1,4-dihydroxy-2-5-bis(pyrazol-1-yl)-benzene) at a Solid Electrode-Aqueous Electrolyte Interface. Journal Of Physical Chemistry B, 104, 9, pp1977-1983. DOI: 10.1021/jp9925942
  2. Forster, R.J.; Figgemeier, E.; Lees, A. C.; Hjelm, J.; Vos, J. G. 2000. Photostability, Electrochemistry and Monolayers of [M(bpy)2 trans-1,2-bis(4-pyridyl)ethylene L]+; M = Ru, Os; L = Cl, H2O. Langmuir, 16, 20, pp7867-7870. DOI: 10.1021/la0007170
  3. Forster, R.J.; Hogan, C.F. 2000. Electrochemiluminescent Metallopolymer Coatings: Combined Light and Current Detection in Flow Injection Analysis. Analytical Chemistry, 72, 22, pp5576-5582. DOI: 10.1021/ac000605d
  4. Forster, R.J.; Keyes, T.E.; Bond, A.M. 2000. Protonation Effects on the Structure and Homogeneous Charge Transport Dynamics of Solid-State Osmium Bis-bipyridyl Tetrazine Chloride Films. Journal Of Physical Chemistry B, 104, 27, pp6389-6396. DOI: 10.1021/jp994275g
  5. Forster, R.J.; Keyes, T.E.; Farrell, M.; O'Hanlon, D. 2000. Impact of Hydrogen Bonding on the Redox Properties of 1-Amino-2-Sulphonic-4-Hydroxy -Anthraquionone Monolayers. Langmuir, 16, 25, pp9871-9877. DOI: 10.1021/la000546z
  6. Forster, R. J.; Keyes, T. E.; Majda, M. 2000. Homogeneous and Heterogeneous Electron Transfer Dynamics of Osmium-Containing Monolayers at the Air/Water Interface. Journal Of Physical Chemistry B, 104, 18, pp4425-4432. DOI: 10.1021/jp9932620
  7. Forster, R.J.; Loughman, P.J.; Keyes, T.E. 2000. Effect of Electrode Density of States on the Heterogeneous Electron Transfer Dynamics of Osmium Containing Monolayers. Journal Of The American Chemical Society, 122, 48, pp11948-11955. DOI: 10.1021/ja002616u
  8. Forster, R. J.; Figgemeier, E.; Loughman, P. J.; Lees, A.C.; Hjelm, J.; Vos, J.G. 2000. Conjugated vs. Non-Conjugated Bridges : Heterogeneous Electron Transfer Dynamics of Osmium Polypyridyl Monolayers.Langmuir, 16, 20, pp7871-7875. DOI: 10.1021/la000718s
  9. O'Hanlon, D.; Forster, R.J. 2000. Intermolecular Hydrogen Bonding: Two-Component Anthraquinone Monolayers. Langmuir, 16, 2, pp702-707. DOI: 10.1021/la990882j
  10. Malins, C.; Glever, H.G.; Keyes, T.E.; Vos, J.G.; Dressic, W.J.; McCraith, B.D. 2000. Sol–gelimmobilisedruthenium(II) polypyridylcomplexes as chemical transducers for opticalpH sensing. Sensors and Actuators B: Chemical,67, 1-2, pp89-95.  DOI: 10.1016/S0925-4005(00)00411-1
  11. Fanni S.; Keyes T.E.; O'Connor C.M.; Hughes, H.; Wang, R.Y.; Vos, J.G. 2000. Excited State Properties of Ruthenium(II) Polypyridyl Complexes Containing Asymmetric Triazole Ligands. Coordination Chemistry Reviews, 208, 1, pp77-86.  DOI: 10.1016/S0010-8545(00)00245-9
  12. Knör, G.; Leirer, M.; Keyes, T.E.; Vos, J.G.; Vogler, A. 2000.  Non-luminescent 1,2-Diiminetricarbonylrhenium(I)chloride Complexes. Synthesis, Electrochemical and Spectroscopic Properties of Re(DIAN)(CO)3Cl with DIAN = p-subtituted Bis(arylimino)acenaphthene. European Journal Of Inorganic
  13.  Chemistry, 2000, 4, pp749-751. DOI: 10.1002/(SICI)1099-0682(200004)2000:4<749::AID-EJIC749>3.0.CO;2-B
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 REVIEWS

  1. Bertoncello, P.; Forster, R.J. 2009. Nanostructured materials for electrochemiluminescence (ECL)-based detection methods: Recent advances and future perspectives.  Biosensors and Bioelectronics, 24, 11, pp3191–3200. DOI: 10.1016/j.bios.2009.02.013
  2. Forster, R.J.; Keyes, T.E. 2009. Photonic interfacial supramolecular assemblies incorporating transition metals. Coordination Chemistry Reviews, 253, 13-14, pp1833–1853. DOI: 10.1016/j.ccr.2009.02.009
  3. Forster, R.J.; Bertoncello, P.; Keyes, T.E. 2009. Electrogenerated Chemiluminescence.  Annual Review of Analytical Chemistry, 2, pp359–385. DOI: 10.1146/annurev-anchem-060908-155305
  4. Fanni, S.; Keyes, T.E.; O'Connor, C.M.; Hughes, H.; Wang, R.; Vos, J.G. 2002.  Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands. Coordination Chemistry Reviews208, 1, pp77-86. DOI: 10.1016/S0010-8545(00)00245-9
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THESES

  1. Gavin Sewell (2014)  Zeolite-Y scafolded Donor Acceptor Pairs for Nanoelectronics. PhD. thesis, Dublin City University.
  2. Emily Reddy (2013) A Novel Role for Thiols in the Regulation of Platelet Function. PhD. thesis, Dublin City University.
  3. Zoe Stack (2013) The synthesis and characterisation of novel ruthenium (ii) polypyridyl complexes for use in cellular imaging. MSc. thesis, Dublin City University.
  4. Lorraine Blackmore (2013) Novel Luminescent Peptide Conjugates for Assessing Protein and other Biomolecules Location and Function. PhD thesis, Dublin City University.
  5. Dolan, Ciaran (2012) The synthesis and characterisation of inorganic and organic luminophores suitable for biomolecule conjugation. PhD thesis, Dublin City University.
  6. Finn, Stephen (2011) Ruthenium polypyridyl complexes with long aliphatic chains; photophysics, interfacial assembly and cell imaging. PhD thesis, Dublin City University.
  7. Spain, Elaine (2011) High sensitivity DNA detection using gold nanoparticles and conducting polymers. PhD thesis, Dublin City University.
  8. Walsh, James J (2011) Association of the Dawson-type polyoxometalates with photoactive transition metal monomers and polymers. PhD thesis, Dublin City University.
  9. Zhu, Jie (2011) [Ru-POM] Photo-electrocatalysis. PhD thesis, Dublin City University.
  10. Devadoss, Anitha (2011) Colloidal gold nanoparticles for high sensitivity ECL biosensors: Effect of size and shape. PhD thesis, Dublin City University.
  11. Jose, Bincy (2011) Biomimetic Photonic Nanocavity Arrays. PhD thesis, Dublin City University.
  12. Venkatanarayanan, Anita (2010) Nano Materials for Electrochemiluminescent Biosensors. PhD thesis, Dublin City University.
  13. Zuliani, Claudio (2010) Nano- and micro- electrodes: applications in the biosensing field. PhD thesis, Dublin City University.
  14. Mallon, Colm (2009) Interfacial electroactive assemblies: from molecular electronics to biological applications. PhD thesis, Dublin City University.
  15. Qiang, Zeng (2009) Assembly and charge transport in interfacial polymeric and supramolecular thin films. PhD thesis, Dublin City University.
  16. Sheridan, Eoin E. (2009) Electrodeposited nanoparticles: properties and photocatalytic applications. PhD thesis, Dublin City University.
  17. O'Reilly, Emmet (2008) Conjugated metallopolymer systems for electrochemiluminescence enhancement: new approaches and materials. PhD thesis, Dublin City University.
  18. Campagnoli, Elena (2007) Immobilisation of redox active molecules as precursors for nanowire self-assembly. PhD thesis, Dublin City University.
  19. Dennany, Lynn (2004) Electrochemiluminescent & amperometric detection of DNA & DNA damage. PhD thesis, Dublin City University.
  20. Farrell, Mary M. (2003) Electroanalysis in the nanodomain: quinone monolayers and nanometer dimensioned electrodes. PhD thesis, Dublin City University.
  21. Brennan, Jennifer L. (2002) Ground and excited state electron transfer dynamics. PhD thesis, Dublin City University.